Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cobalt(II) dihydrate

The title complex, [Co(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, has site symmetry 2 with the Co(II) cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyl­eneamino)benzene­sulfonate (paba) ligands chelate to the Co(II) cation in a distorted octa­hedral geometry. The pyridine and benzene...

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Detalles Bibliográficos
Autores principales: Huang, Xue-Ren, Ou-Yang, Miao, Yang, Ge-Ge, Meng, Xiu-Jin, Jiang, Yi-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971130/
https://www.ncbi.nlm.nih.gov/pubmed/21578190
http://dx.doi.org/10.1107/S1600536809043918
Descripción
Sumario:The title complex, [Co(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, has site symmetry 2 with the Co(II) cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyl­eneamino)benzene­sulfonate (paba) ligands chelate to the Co(II) cation in a distorted octa­hedral geometry. The pyridine and benzene rings in the paba ligand are oriented at a dihedral angle of 42.86 (13)°. Inter­molecular O—H⋯O and C—H⋯O hydrogen bonding is present in the crystal structure.

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