Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cobalt(II) dihydrate

The title complex, [Co(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, has site symmetry 2 with the Co(II) cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyl­eneamino)benzene­sulfonate (paba) ligands chelate to the Co(II) cation in a distorted octa­hedral geometry. The pyridine and benzene...

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Autores principales: Huang, Xue-Ren, Ou-Yang, Miao, Yang, Ge-Ge, Meng, Xiu-Jin, Jiang, Yi-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971130/
https://www.ncbi.nlm.nih.gov/pubmed/21578190
http://dx.doi.org/10.1107/S1600536809043918
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author Huang, Xue-Ren
Ou-Yang, Miao
Yang, Ge-Ge
Meng, Xiu-Jin
Jiang, Yi-Min
author_facet Huang, Xue-Ren
Ou-Yang, Miao
Yang, Ge-Ge
Meng, Xiu-Jin
Jiang, Yi-Min
author_sort Huang, Xue-Ren
collection PubMed
description The title complex, [Co(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, has site symmetry 2 with the Co(II) cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyl­eneamino)benzene­sulfonate (paba) ligands chelate to the Co(II) cation in a distorted octa­hedral geometry. The pyridine and benzene rings in the paba ligand are oriented at a dihedral angle of 42.86 (13)°. Inter­molecular O—H⋯O and C—H⋯O hydrogen bonding is present in the crystal structure.
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spelling pubmed-29711302010-12-30 Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cobalt(II) dihydrate Huang, Xue-Ren Ou-Yang, Miao Yang, Ge-Ge Meng, Xiu-Jin Jiang, Yi-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, has site symmetry 2 with the Co(II) cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyl­eneamino)benzene­sulfonate (paba) ligands chelate to the Co(II) cation in a distorted octa­hedral geometry. The pyridine and benzene rings in the paba ligand are oriented at a dihedral angle of 42.86 (13)°. Inter­molecular O—H⋯O and C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971130/ /pubmed/21578190 http://dx.doi.org/10.1107/S1600536809043918 Text en © Huang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Xue-Ren
Ou-Yang, Miao
Yang, Ge-Ge
Meng, Xiu-Jin
Jiang, Yi-Min
Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cobalt(II) dihydrate
title Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cobalt(II) dihydrate
title_full Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cobalt(II) dihydrate
title_fullStr Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cobalt(II) dihydrate
title_full_unstemmed Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cobalt(II) dihydrate
title_short Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cobalt(II) dihydrate
title_sort bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) n,n′,o]cobalt(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971130/
https://www.ncbi.nlm.nih.gov/pubmed/21578190
http://dx.doi.org/10.1107/S1600536809043918
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