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Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ(2) N,N′)copper(II)]
In the title complex, [Cu(2)Cl(4)(C(17)H(22)N(2))(2)], the Cu(II) cation is coordinated by a N,N′-dibenzylpropane-1,2-diamine ligand and two Cl(−) anions, and a Cl(−) anion from an adjacent molecule further bridges to the Cu(II) cation in the apical position, with a longer Cu—Cl distance of 2.9858...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971131/ https://www.ncbi.nlm.nih.gov/pubmed/21578213 http://dx.doi.org/10.1107/S1600536809044997 |
| _version_ | 1782190553472958464 |
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| author | Liu, Yu-Fen Rong, Da-Fu Xia, Hai-Tao Wang, Da-Qi |
| author_facet | Liu, Yu-Fen Rong, Da-Fu Xia, Hai-Tao Wang, Da-Qi |
| author_sort | Liu, Yu-Fen |
| collection | PubMed |
| description | In the title complex, [Cu(2)Cl(4)(C(17)H(22)N(2))(2)], the Cu(II) cation is coordinated by a N,N′-dibenzylpropane-1,2-diamine ligand and two Cl(−) anions, and a Cl(−) anion from an adjacent molecule further bridges to the Cu(II) cation in the apical position, with a longer Cu—Cl distance of 2.9858 (18) Å, forming a centrosymmetric dimeric complex in which each Cu(II) cation is in a distorted square-pyramidal geometry. Intramolecular N—H⋯Cl hydrogen bonding is observed in the dimeric complex. |
| format | Text |
| id | pubmed-2971131 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29711312010-12-30 Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ(2) N,N′)copper(II)] Liu, Yu-Fen Rong, Da-Fu Xia, Hai-Tao Wang, Da-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(2)Cl(4)(C(17)H(22)N(2))(2)], the Cu(II) cation is coordinated by a N,N′-dibenzylpropane-1,2-diamine ligand and two Cl(−) anions, and a Cl(−) anion from an adjacent molecule further bridges to the Cu(II) cation in the apical position, with a longer Cu—Cl distance of 2.9858 (18) Å, forming a centrosymmetric dimeric complex in which each Cu(II) cation is in a distorted square-pyramidal geometry. Intramolecular N—H⋯Cl hydrogen bonding is observed in the dimeric complex. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971131/ /pubmed/21578213 http://dx.doi.org/10.1107/S1600536809044997 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Yu-Fen Rong, Da-Fu Xia, Hai-Tao Wang, Da-Qi Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ(2) N,N′)copper(II)] |
| title | Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ(2)
N,N′)copper(II)] |
| title_full | Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ(2)
N,N′)copper(II)] |
| title_fullStr | Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ(2)
N,N′)copper(II)] |
| title_full_unstemmed | Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ(2)
N,N′)copper(II)] |
| title_short | Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ(2)
N,N′)copper(II)] |
| title_sort | di-μ-chlorido-bis[chlorido(n,n′-dibenzylpropane-1,2-diamine-κ(2)
n,n′)copper(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971131/ https://www.ncbi.nlm.nih.gov/pubmed/21578213 http://dx.doi.org/10.1107/S1600536809044997 |
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