Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II)

In the title cobalt(II) complex with 2-methyl­anilinium and diphosphate, (C(7)H(10)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], a three-dimensional network is built up from anionic layers of [Co(H(2)P(2)O(7))(2)(H(2)O)(2)](2−) units and 2-methyl­anilinium cations located between these layers. The dihydroge...

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Detalles Bibliográficos
Autores principales: Selmi, Ahmed, Akriche, Samah, Rzaigui, Mohamed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971134/
https://www.ncbi.nlm.nih.gov/pubmed/21578209
http://dx.doi.org/10.1107/S1600536809044079
Descripción
Sumario:In the title cobalt(II) complex with 2-methyl­anilinium and diphosphate, (C(7)H(10)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], a three-dimensional network is built up from anionic layers of [Co(H(2)P(2)O(7))(2)(H(2)O)(2)](2−) units and 2-methyl­anilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co(2+) ions lie on inversion centers. An intricate network of O—H⋯O and N—H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other inter­actions, being of electrostatic and van der Waals nature.

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