Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II)

In the title cobalt(II) complex with 2-methyl­anilinium and diphosphate, (C(7)H(10)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], a three-dimensional network is built up from anionic layers of [Co(H(2)P(2)O(7))(2)(H(2)O)(2)](2−) units and 2-methyl­anilinium cations located between these layers. The dihydroge...

Descripción completa

Detalles Bibliográficos
Autores principales: Selmi, Ahmed, Akriche, Samah, Rzaigui, Mohamed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971134/
https://www.ncbi.nlm.nih.gov/pubmed/21578209
http://dx.doi.org/10.1107/S1600536809044079
_version_ 1782190554154532864
author Selmi, Ahmed
Akriche, Samah
Rzaigui, Mohamed
author_facet Selmi, Ahmed
Akriche, Samah
Rzaigui, Mohamed
author_sort Selmi, Ahmed
collection PubMed
description In the title cobalt(II) complex with 2-methyl­anilinium and diphosphate, (C(7)H(10)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], a three-dimensional network is built up from anionic layers of [Co(H(2)P(2)O(7))(2)(H(2)O)(2)](2−) units and 2-methyl­anilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co(2+) ions lie on inversion centers. An intricate network of O—H⋯O and N—H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other inter­actions, being of electrostatic and van der Waals nature.
format Text
id pubmed-2971134
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29711342010-12-30 Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II) Selmi, Ahmed Akriche, Samah Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title cobalt(II) complex with 2-methyl­anilinium and diphosphate, (C(7)H(10)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], a three-dimensional network is built up from anionic layers of [Co(H(2)P(2)O(7))(2)(H(2)O)(2)](2−) units and 2-methyl­anilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co(2+) ions lie on inversion centers. An intricate network of O—H⋯O and N—H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other inter­actions, being of electrostatic and van der Waals nature. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971134/ /pubmed/21578209 http://dx.doi.org/10.1107/S1600536809044079 Text en © Selmi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Selmi, Ahmed
Akriche, Samah
Rzaigui, Mohamed
Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II)
title Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II)
title_full Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II)
title_fullStr Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II)
title_full_unstemmed Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II)
title_short Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II)
title_sort bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971134/
https://www.ncbi.nlm.nih.gov/pubmed/21578209
http://dx.doi.org/10.1107/S1600536809044079
work_keys_str_mv AT selmiahmed bis2methylaniliniumdiaquabisdihydrogendiphosphato2cobaltateii
AT akrichesamah bis2methylaniliniumdiaquabisdihydrogendiphosphato2cobaltateii
AT rzaiguimohamed bis2methylaniliniumdiaquabisdihydrogendiphosphato2cobaltateii

Ejemplares similares