(η(6)-p-Cymene)bis­(trichlorido­stannyl)(triethoxy­phosphine-κP)ruthenium(II)

In the title complex, [RuSn(2)(C(10)H(14))Cl(6)(C(6)H(15)O(3)P)], the Ru—Sn bond lengths [2.5619 (3) and 2.5669 (3) Å] are about 0.3 Å shorter than the sum of the covalent Ru and Sn radii (1.46 + 1.39 = 2.85 Å), in line with other structurally characterized arene ruthenium trichlorido­stannyl deriva...

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Detalles Bibliográficos
Autores principales: Shapovalov, Sergey S., Therrien, Bruno
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971135/
https://www.ncbi.nlm.nih.gov/pubmed/21578155
http://dx.doi.org/10.1107/S1600536809042986
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author Shapovalov, Sergey S.
Therrien, Bruno
author_facet Shapovalov, Sergey S.
Therrien, Bruno
author_sort Shapovalov, Sergey S.
collection PubMed
description In the title complex, [RuSn(2)(C(10)H(14))Cl(6)(C(6)H(15)O(3)P)], the Ru—Sn bond lengths [2.5619 (3) and 2.5669 (3) Å] are about 0.3 Å shorter than the sum of the covalent Ru and Sn radii (1.46 + 1.39 = 2.85 Å), in line with other structurally characterized arene ruthenium trichlorido­stannyl derivatives. The Ru(II) atom is surrounded by a para-cymene, a triethylphosphite and two trichloridostannyl ligands in a typical piano-stool coordination.
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spelling pubmed-29711352010-12-30 (η(6)-p-Cymene)bis­(trichlorido­stannyl)(triethoxy­phosphine-κP)ruthenium(II) Shapovalov, Sergey S. Therrien, Bruno Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [RuSn(2)(C(10)H(14))Cl(6)(C(6)H(15)O(3)P)], the Ru—Sn bond lengths [2.5619 (3) and 2.5669 (3) Å] are about 0.3 Å shorter than the sum of the covalent Ru and Sn radii (1.46 + 1.39 = 2.85 Å), in line with other structurally characterized arene ruthenium trichlorido­stannyl derivatives. The Ru(II) atom is surrounded by a para-cymene, a triethylphosphite and two trichloridostannyl ligands in a typical piano-stool coordination. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971135/ /pubmed/21578155 http://dx.doi.org/10.1107/S1600536809042986 Text en © Shapovalov and Therrien 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shapovalov, Sergey S.
Therrien, Bruno
(η(6)-p-Cymene)bis­(trichlorido­stannyl)(triethoxy­phosphine-κP)ruthenium(II)
title (η(6)-p-Cymene)bis­(trichlorido­stannyl)(triethoxy­phosphine-κP)ruthenium(II)
title_full (η(6)-p-Cymene)bis­(trichlorido­stannyl)(triethoxy­phosphine-κP)ruthenium(II)
title_fullStr (η(6)-p-Cymene)bis­(trichlorido­stannyl)(triethoxy­phosphine-κP)ruthenium(II)
title_full_unstemmed (η(6)-p-Cymene)bis­(trichlorido­stannyl)(triethoxy­phosphine-κP)ruthenium(II)
title_short (η(6)-p-Cymene)bis­(trichlorido­stannyl)(triethoxy­phosphine-κP)ruthenium(II)
title_sort (η(6)-p-cymene)bis­(trichlorido­stannyl)(triethoxy­phosphine-κp)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971135/
https://www.ncbi.nlm.nih.gov/pubmed/21578155
http://dx.doi.org/10.1107/S1600536809042986
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