(5Z)-5-(2-Hydroxy­benzyl­idene)-2-thioxo-1,3-thia­zolidin-4-one methanol hemisolvate

In the title compound, C(10)H(7)NO(2)S(2)·0.5CH(3)OH, the dihedral angle between the aromatic rings is 11.43 (11)° and a short intra­molecular C—H⋯S contact occurs. The methanol solvent mol­ecule is equally disordered over two sets of sites. In the crystal, inversion dimers linked by pairs of N—H⋯O...

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Detalles Bibliográficos
Autores principales: Shahwar, Durre, Tahir, M. Nawaz, Raza, Muhammad Asam, Iqbal, Bushra, Naz, Sana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971136/
https://www.ncbi.nlm.nih.gov/pubmed/21578252
http://dx.doi.org/10.1107/S1600536809039555
Descripción
Sumario:In the title compound, C(10)H(7)NO(2)S(2)·0.5CH(3)OH, the dihedral angle between the aromatic rings is 11.43 (11)° and a short intra­molecular C—H⋯S contact occurs. The methanol solvent mol­ecule is equally disordered over two sets of sites. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds occur. The methanol solvent mol­ecule connects the dimers through O—H⋯S and O—H⋯O inter­molecular hydrogen bonds. Further stability is afforded by C—H⋯π and π–π inter­actions [centroid–centroid separation = 3.5948 (13) Å].

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