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Bis[6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolate-κO (1)]tris(nitrato-κ(2) O,O′)ytterbium(III) monohydrate
The crystal structure of title compound, [Yb(NO(3))(3)(C(15)H(15)NO(2))(2)]·H(2)O, contains two Schiff base 2-[(4-methylphenyl)iminomethyl]-6-methoxyphenol (HL) ligands, three independent nitrate ions that chelate to the ytterbium(III) ion in an O,O′-bidentate manner and an uncoordinated water...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971141/ https://www.ncbi.nlm.nih.gov/pubmed/21578132 http://dx.doi.org/10.1107/S1600536809041361 |
Sumario: | The crystal structure of title compound, [Yb(NO(3))(3)(C(15)H(15)NO(2))(2)]·H(2)O, contains two Schiff base 2-[(4-methylphenyl)iminomethyl]-6-methoxyphenol (HL) ligands, three independent nitrate ions that chelate to the ytterbium(III) ion in an O,O′-bidentate manner and an uncoordinated water molecule. The coordination number of the Yb(III) ion is eight. The HL ligands chelate with a strong Yb—O(phenolate) bond and a weak Yb—O(methoxy) contact. The latter augments the coordination polyhedron to give a YbO(10) bicapped square antiprism. Classical intermolecular O—H⋯O and N—H⋯O hydrogen bonds as well as weak C—H⋯O contacts contribute to the stability of the structure. |
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