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Bis[6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolate-κO (1)]tris(nitrato-κ(2) O,O′)ytterbium(III) monohydrate
The crystal structure of title compound, [Yb(NO(3))(3)(C(15)H(15)NO(2))(2)]·H(2)O, contains two Schiff base 2-[(4-methylphenyl)iminomethyl]-6-methoxyphenol (HL) ligands, three independent nitrate ions that chelate to the ytterbium(III) ion in an O,O′-bidentate manner and an uncoordinated water...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971141/ https://www.ncbi.nlm.nih.gov/pubmed/21578132 http://dx.doi.org/10.1107/S1600536809041361 |
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author | Liu, Jian-Feng Liu, Jia-Lu Zhao, Guo-Liang |
author_facet | Liu, Jian-Feng Liu, Jia-Lu Zhao, Guo-Liang |
author_sort | Liu, Jian-Feng |
collection | PubMed |
description | The crystal structure of title compound, [Yb(NO(3))(3)(C(15)H(15)NO(2))(2)]·H(2)O, contains two Schiff base 2-[(4-methylphenyl)iminomethyl]-6-methoxyphenol (HL) ligands, three independent nitrate ions that chelate to the ytterbium(III) ion in an O,O′-bidentate manner and an uncoordinated water molecule. The coordination number of the Yb(III) ion is eight. The HL ligands chelate with a strong Yb—O(phenolate) bond and a weak Yb—O(methoxy) contact. The latter augments the coordination polyhedron to give a YbO(10) bicapped square antiprism. Classical intermolecular O—H⋯O and N—H⋯O hydrogen bonds as well as weak C—H⋯O contacts contribute to the stability of the structure. |
format | Text |
id | pubmed-2971141 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29711412010-12-30 Bis[6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolate-κO (1)]tris(nitrato-κ(2) O,O′)ytterbium(III) monohydrate Liu, Jian-Feng Liu, Jia-Lu Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of title compound, [Yb(NO(3))(3)(C(15)H(15)NO(2))(2)]·H(2)O, contains two Schiff base 2-[(4-methylphenyl)iminomethyl]-6-methoxyphenol (HL) ligands, three independent nitrate ions that chelate to the ytterbium(III) ion in an O,O′-bidentate manner and an uncoordinated water molecule. The coordination number of the Yb(III) ion is eight. The HL ligands chelate with a strong Yb—O(phenolate) bond and a weak Yb—O(methoxy) contact. The latter augments the coordination polyhedron to give a YbO(10) bicapped square antiprism. Classical intermolecular O—H⋯O and N—H⋯O hydrogen bonds as well as weak C—H⋯O contacts contribute to the stability of the structure. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971141/ /pubmed/21578132 http://dx.doi.org/10.1107/S1600536809041361 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Jian-Feng Liu, Jia-Lu Zhao, Guo-Liang Bis[6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolate-κO (1)]tris(nitrato-κ(2) O,O′)ytterbium(III) monohydrate |
title | Bis[6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolate-κO
(1)]tris(nitrato-κ(2)
O,O′)ytterbium(III) monohydrate |
title_full | Bis[6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolate-κO
(1)]tris(nitrato-κ(2)
O,O′)ytterbium(III) monohydrate |
title_fullStr | Bis[6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolate-κO
(1)]tris(nitrato-κ(2)
O,O′)ytterbium(III) monohydrate |
title_full_unstemmed | Bis[6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolate-κO
(1)]tris(nitrato-κ(2)
O,O′)ytterbium(III) monohydrate |
title_short | Bis[6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolate-κO
(1)]tris(nitrato-κ(2)
O,O′)ytterbium(III) monohydrate |
title_sort | bis[6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolate-κo
(1)]tris(nitrato-κ(2)
o,o′)ytterbium(iii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971141/ https://www.ncbi.nlm.nih.gov/pubmed/21578132 http://dx.doi.org/10.1107/S1600536809041361 |
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