Cargando…

Bis[6-meth­oxy-2-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κO (1)]tris­(nitrato-κ(2) O,O′)ytterbium(III) monohydrate

The crystal structure of title compound, [Yb(NO(3))(3)(C(15)H(15)NO(2))(2)]·H(2)O, contains two Schiff base 2-[(4-methyl­phen­yl)imino­meth­yl]-6-methoxy­phenol (HL) ligands, three independent nitrate ions that chelate to the ytterbium(III) ion in an O,O′-bidentate manner and an uncoordinated water...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Jian-Feng, Liu, Jia-Lu, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971141/
https://www.ncbi.nlm.nih.gov/pubmed/21578132
http://dx.doi.org/10.1107/S1600536809041361
_version_ 1782190555806040064
author Liu, Jian-Feng
Liu, Jia-Lu
Zhao, Guo-Liang
author_facet Liu, Jian-Feng
Liu, Jia-Lu
Zhao, Guo-Liang
author_sort Liu, Jian-Feng
collection PubMed
description The crystal structure of title compound, [Yb(NO(3))(3)(C(15)H(15)NO(2))(2)]·H(2)O, contains two Schiff base 2-[(4-methyl­phen­yl)imino­meth­yl]-6-methoxy­phenol (HL) ligands, three independent nitrate ions that chelate to the ytterbium(III) ion in an O,O′-bidentate manner and an uncoordinated water mol­ecule. The coordination number of the Yb(III) ion is eight. The HL ligands chelate with a strong Yb—O(phenolate) bond and a weak Yb—O(meth­oxy) contact. The latter augments the coordination polyhedron to give a YbO(10) bicapped square antiprism. Classical inter­molecular O—H⋯O and N—H⋯O hydrogen bonds as well as weak C—H⋯O contacts contribute to the stability of the structure.
format Text
id pubmed-2971141
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29711412010-12-30 Bis[6-meth­oxy-2-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κO (1)]tris­(nitrato-κ(2) O,O′)ytterbium(III) monohydrate Liu, Jian-Feng Liu, Jia-Lu Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of title compound, [Yb(NO(3))(3)(C(15)H(15)NO(2))(2)]·H(2)O, contains two Schiff base 2-[(4-methyl­phen­yl)imino­meth­yl]-6-methoxy­phenol (HL) ligands, three independent nitrate ions that chelate to the ytterbium(III) ion in an O,O′-bidentate manner and an uncoordinated water mol­ecule. The coordination number of the Yb(III) ion is eight. The HL ligands chelate with a strong Yb—O(phenolate) bond and a weak Yb—O(meth­oxy) contact. The latter augments the coordination polyhedron to give a YbO(10) bicapped square antiprism. Classical inter­molecular O—H⋯O and N—H⋯O hydrogen bonds as well as weak C—H⋯O contacts contribute to the stability of the structure. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971141/ /pubmed/21578132 http://dx.doi.org/10.1107/S1600536809041361 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Jian-Feng
Liu, Jia-Lu
Zhao, Guo-Liang
Bis[6-meth­oxy-2-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κO (1)]tris­(nitrato-κ(2) O,O′)ytterbium(III) monohydrate
title Bis[6-meth­oxy-2-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κO (1)]tris­(nitrato-κ(2) O,O′)ytterbium(III) monohydrate
title_full Bis[6-meth­oxy-2-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κO (1)]tris­(nitrato-κ(2) O,O′)ytterbium(III) monohydrate
title_fullStr Bis[6-meth­oxy-2-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κO (1)]tris­(nitrato-κ(2) O,O′)ytterbium(III) monohydrate
title_full_unstemmed Bis[6-meth­oxy-2-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κO (1)]tris­(nitrato-κ(2) O,O′)ytterbium(III) monohydrate
title_short Bis[6-meth­oxy-2-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κO (1)]tris­(nitrato-κ(2) O,O′)ytterbium(III) monohydrate
title_sort bis[6-meth­oxy-2-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κo (1)]tris­(nitrato-κ(2) o,o′)ytterbium(iii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971141/
https://www.ncbi.nlm.nih.gov/pubmed/21578132
http://dx.doi.org/10.1107/S1600536809041361
work_keys_str_mv AT liujianfeng bis6methoxy24methylphenyliminiomethylphenolateko1trisnitratok2ooytterbiumiiimonohydrate
AT liujialu bis6methoxy24methylphenyliminiomethylphenolateko1trisnitratok2ooytterbiumiiimonohydrate
AT zhaoguoliang bis6methoxy24methylphenyliminiomethylphenolateko1trisnitratok2ooytterbiumiiimonohydrate