Tetra­aqua­bis­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) dimethyl­formamide disolvate dihydrate

In the mononuclear title compound, [Co(C(9)H(4)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, the Co(II) atom, which lies on a center of inversion, is coordinated by four water mol­ecules and two N atoms from two two symmetry-related 1H-benzimidazole-5,6-dicarboxyl­ate ligands in a distorted octa­hedra...

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Detalles Bibliográficos
Autores principales: Wang, Hao, Song, Wen-Dong, Li, Shi-Jie, Miao, Dong-Liang, Liu, Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971142/
https://www.ncbi.nlm.nih.gov/pubmed/21578159
http://dx.doi.org/10.1107/S1600536809043177
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author Wang, Hao
Song, Wen-Dong
Li, Shi-Jie
Miao, Dong-Liang
Liu, Jin
author_facet Wang, Hao
Song, Wen-Dong
Li, Shi-Jie
Miao, Dong-Liang
Liu, Jin
author_sort Wang, Hao
collection PubMed
description In the mononuclear title compound, [Co(C(9)H(4)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, the Co(II) atom, which lies on a center of inversion, is coordinated by four water mol­ecules and two N atoms from two two symmetry-related 1H-benzimidazole-5,6-dicarboxyl­ate ligands in a distorted octa­hedral geometry. The packing is governed by inter­molecular O—H⋯O and N—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-29711422010-12-30 Tetra­aqua­bis­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) dimethyl­formamide disolvate dihydrate Wang, Hao Song, Wen-Dong Li, Shi-Jie Miao, Dong-Liang Liu, Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [Co(C(9)H(4)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, the Co(II) atom, which lies on a center of inversion, is coordinated by four water mol­ecules and two N atoms from two two symmetry-related 1H-benzimidazole-5,6-dicarboxyl­ate ligands in a distorted octa­hedral geometry. The packing is governed by inter­molecular O—H⋯O and N—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971142/ /pubmed/21578159 http://dx.doi.org/10.1107/S1600536809043177 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hao
Song, Wen-Dong
Li, Shi-Jie
Miao, Dong-Liang
Liu, Jin
Tetra­aqua­bis­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) dimethyl­formamide disolvate dihydrate
title Tetra­aqua­bis­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) dimethyl­formamide disolvate dihydrate
title_full Tetra­aqua­bis­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) dimethyl­formamide disolvate dihydrate
title_fullStr Tetra­aqua­bis­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) dimethyl­formamide disolvate dihydrate
title_full_unstemmed Tetra­aqua­bis­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) dimethyl­formamide disolvate dihydrate
title_short Tetra­aqua­bis­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) dimethyl­formamide disolvate dihydrate
title_sort tetra­aqua­bis­(1h-benzimidazole-5,6-di­carboxyl­ato-κn (3))cobalt(ii) dimethyl­formamide disolvate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971142/
https://www.ncbi.nlm.nih.gov/pubmed/21578159
http://dx.doi.org/10.1107/S1600536809043177
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