2-Bromo-N′-[(2Z)-butan-2-yl­idene]-5-methoxy­benzohydrazide

In the title compound, C(12)H(15)BrN(2)O(2), the dihedral angle between the benzene ring and the mean plane of the amide grouping is 77.7 (8)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds occur, and the packing is further supported by C—H⋯O and C—H⋯Br inter­actions and w...

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Autores principales: Jasinski, Jerry P., Butcher, Ray J., Suchitra, L. P., Yathirajan, H. S., Narayana, B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971143/
https://www.ncbi.nlm.nih.gov/pubmed/21578539
http://dx.doi.org/10.1107/S1600536809044869
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author Jasinski, Jerry P.
Butcher, Ray J.
Suchitra, L. P.
Yathirajan, H. S.
Narayana, B.
author_facet Jasinski, Jerry P.
Butcher, Ray J.
Suchitra, L. P.
Yathirajan, H. S.
Narayana, B.
author_sort Jasinski, Jerry P.
collection PubMed
description In the title compound, C(12)H(15)BrN(2)O(2), the dihedral angle between the benzene ring and the mean plane of the amide grouping is 77.7 (8)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds occur, and the packing is further supported by C—H⋯O and C—H⋯Br inter­actions and weak π–π ring stacking inter­actions.
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spelling pubmed-29711432010-12-30 2-Bromo-N′-[(2Z)-butan-2-yl­idene]-5-methoxy­benzohydrazide Jasinski, Jerry P. Butcher, Ray J. Suchitra, L. P. Yathirajan, H. S. Narayana, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(15)BrN(2)O(2), the dihedral angle between the benzene ring and the mean plane of the amide grouping is 77.7 (8)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds occur, and the packing is further supported by C—H⋯O and C—H⋯Br inter­actions and weak π–π ring stacking inter­actions. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971143/ /pubmed/21578539 http://dx.doi.org/10.1107/S1600536809044869 Text en © Jasinski et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jasinski, Jerry P.
Butcher, Ray J.
Suchitra, L. P.
Yathirajan, H. S.
Narayana, B.
2-Bromo-N′-[(2Z)-butan-2-yl­idene]-5-methoxy­benzohydrazide
title 2-Bromo-N′-[(2Z)-butan-2-yl­idene]-5-methoxy­benzohydrazide
title_full 2-Bromo-N′-[(2Z)-butan-2-yl­idene]-5-methoxy­benzohydrazide
title_fullStr 2-Bromo-N′-[(2Z)-butan-2-yl­idene]-5-methoxy­benzohydrazide
title_full_unstemmed 2-Bromo-N′-[(2Z)-butan-2-yl­idene]-5-methoxy­benzohydrazide
title_short 2-Bromo-N′-[(2Z)-butan-2-yl­idene]-5-methoxy­benzohydrazide
title_sort 2-bromo-n′-[(2z)-butan-2-yl­idene]-5-methoxy­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971143/
https://www.ncbi.nlm.nih.gov/pubmed/21578539
http://dx.doi.org/10.1107/S1600536809044869
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