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6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thienyl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline
In the title molecule, C(29)H(22)ClN(3)S, the quinoline ring system, thiophene ring and phenyl ring substituents are inclined at angles of 71.70 (7), 59.26 (9) and 81.61 (9)°, respectively, to the 4,5-dihydropyrazole ring. In the 4-phenylquinoline ring system, the phenyl ring makes a dihedral an...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971145/ https://www.ncbi.nlm.nih.gov/pubmed/21578307 http://dx.doi.org/10.1107/S1600536809040239 |
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author | Fun, Hoong-Kun Quah, Ching Kheng Sarveswari, S. Vijayakumar, V. Prasath, R. |
author_facet | Fun, Hoong-Kun Quah, Ching Kheng Sarveswari, S. Vijayakumar, V. Prasath, R. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title molecule, C(29)H(22)ClN(3)S, the quinoline ring system, thiophene ring and phenyl ring substituents are inclined at angles of 71.70 (7), 59.26 (9) and 81.61 (9)°, respectively, to the 4,5-dihydropyrazole ring. In the 4-phenylquinoline ring system, the phenyl ring makes a dihedral angle of 62.49 (7)° with mean plane of quinoline ring system. In the crystal structure, molecules are linked via weak intermolecular C—H⋯N hydrogen bonds, forming an extended one-dimensional chain along the b axis and are further consolidated by C—H⋯π and π–π stacking interactions [centroid–centroid distances = 3.7022 (10) Å]. |
format | Text |
id | pubmed-2971145 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29711452010-12-30 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thienyl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline Fun, Hoong-Kun Quah, Ching Kheng Sarveswari, S. Vijayakumar, V. Prasath, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(29)H(22)ClN(3)S, the quinoline ring system, thiophene ring and phenyl ring substituents are inclined at angles of 71.70 (7), 59.26 (9) and 81.61 (9)°, respectively, to the 4,5-dihydropyrazole ring. In the 4-phenylquinoline ring system, the phenyl ring makes a dihedral angle of 62.49 (7)° with mean plane of quinoline ring system. In the crystal structure, molecules are linked via weak intermolecular C—H⋯N hydrogen bonds, forming an extended one-dimensional chain along the b axis and are further consolidated by C—H⋯π and π–π stacking interactions [centroid–centroid distances = 3.7022 (10) Å]. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971145/ /pubmed/21578307 http://dx.doi.org/10.1107/S1600536809040239 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Quah, Ching Kheng Sarveswari, S. Vijayakumar, V. Prasath, R. 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thienyl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline |
title | 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thienyl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline |
title_full | 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thienyl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline |
title_fullStr | 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thienyl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline |
title_full_unstemmed | 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thienyl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline |
title_short | 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thienyl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline |
title_sort | 6-chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thienyl)-4,5-dihydro-1h-pyrazol-3-yl]quinoline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971145/ https://www.ncbi.nlm.nih.gov/pubmed/21578307 http://dx.doi.org/10.1107/S1600536809040239 |
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