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6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien­yl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline

In the title mol­ecule, C(29)H(22)ClN(3)S, the quinoline ring system, thio­phene ring and phenyl ring substituents are inclined at angles of 71.70 (7), 59.26 (9) and 81.61 (9)°, respectively, to the 4,5-dihydro­pyrazole ring. In the 4-phenyl­quinoline ring system, the phenyl ring makes a dihedral an...

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Autores principales: Fun, Hoong-Kun, Quah, Ching Kheng, Sarveswari, S., Vijayakumar, V., Prasath, R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971145/
https://www.ncbi.nlm.nih.gov/pubmed/21578307
http://dx.doi.org/10.1107/S1600536809040239
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author Fun, Hoong-Kun
Quah, Ching Kheng
Sarveswari, S.
Vijayakumar, V.
Prasath, R.
author_facet Fun, Hoong-Kun
Quah, Ching Kheng
Sarveswari, S.
Vijayakumar, V.
Prasath, R.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title mol­ecule, C(29)H(22)ClN(3)S, the quinoline ring system, thio­phene ring and phenyl ring substituents are inclined at angles of 71.70 (7), 59.26 (9) and 81.61 (9)°, respectively, to the 4,5-dihydro­pyrazole ring. In the 4-phenyl­quinoline ring system, the phenyl ring makes a dihedral angle of 62.49 (7)° with mean plane of quinoline ring system. In the crystal structure, mol­ecules are linked via weak inter­molecular C—H⋯N hydrogen bonds, forming an extended one-dimensional chain along the b axis and are further consolidated by C—H⋯π and π–π stacking inter­actions [centroid–centroid distances = 3.7022 (10) Å].
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spelling pubmed-29711452010-12-30 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien­yl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline Fun, Hoong-Kun Quah, Ching Kheng Sarveswari, S. Vijayakumar, V. Prasath, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(29)H(22)ClN(3)S, the quinoline ring system, thio­phene ring and phenyl ring substituents are inclined at angles of 71.70 (7), 59.26 (9) and 81.61 (9)°, respectively, to the 4,5-dihydro­pyrazole ring. In the 4-phenyl­quinoline ring system, the phenyl ring makes a dihedral angle of 62.49 (7)° with mean plane of quinoline ring system. In the crystal structure, mol­ecules are linked via weak inter­molecular C—H⋯N hydrogen bonds, forming an extended one-dimensional chain along the b axis and are further consolidated by C—H⋯π and π–π stacking inter­actions [centroid–centroid distances = 3.7022 (10) Å]. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971145/ /pubmed/21578307 http://dx.doi.org/10.1107/S1600536809040239 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Quah, Ching Kheng
Sarveswari, S.
Vijayakumar, V.
Prasath, R.
6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien­yl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline
title 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien­yl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline
title_full 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien­yl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline
title_fullStr 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien­yl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline
title_full_unstemmed 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien­yl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline
title_short 6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien­yl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline
title_sort 6-chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien­yl)-4,5-dihydro-1h-pyrazol-3-yl]quinoline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971145/
https://www.ncbi.nlm.nih.gov/pubmed/21578307
http://dx.doi.org/10.1107/S1600536809040239
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