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(5-Ethenyl-1-aza­bicyclo­[2.2.2]octan-2-yl)(6-meth­oxy-3-quinol­yl)methanol methanol solvate

In the title methanol solvate, C(20)H(24)N(2)O(2)·CH(4)O, an L-shaped conformation is found as the two substituents at the central hydr­oxy group are almost orthogonal to each other [the C—C—C angle at the central sp (3)-C atom is 110.12 (13)°]. The most notable feature of the crystal packing is the...

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Detalles Bibliográficos
Autores principales: Muramulla, Savitha, Arman, Hadi D., Zhao, Cong-Gui, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971146/
https://www.ncbi.nlm.nih.gov/pubmed/21578533
http://dx.doi.org/10.1107/S1600536809045073
Descripción
Sumario:In the title methanol solvate, C(20)H(24)N(2)O(2)·CH(4)O, an L-shaped conformation is found as the two substituents at the central hydr­oxy group are almost orthogonal to each other [the C—C—C angle at the central sp (3)-C atom is 110.12 (13)°]. The most notable feature of the crystal packing is the formation of supra­molecular chains along the b direction mediated by O—H⋯N hydrogen bonds occurring between the hydr­oxy and quinoline N atoms; the methanol mol­ecules are linked to these chains via O—H⋯N(amine) hydrogen bonds. C—H⋯O inter­actions also occur.