catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]

In the title compound, {[Cu(C(10)H(14)N(4)Se)(2)](ClO(4))(2)}(n), the Cu(II) ion is located on a twofold rotation axis and has a tetra­gonally distorted square-planar geometry constituted by four N atoms. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide (L) ligands bridges the copper centers int...

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Detalles Bibliográficos
Autores principales: Seredyuk, Maksym, Haukka, Matti, Pavlenko, Vadim A., Fritsky, Igor O.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971148/
https://www.ncbi.nlm.nih.gov/pubmed/21578140
http://dx.doi.org/10.1107/S1600536809042056
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author Seredyuk, Maksym
Haukka, Matti
Pavlenko, Vadim A.
Fritsky, Igor O.
author_facet Seredyuk, Maksym
Haukka, Matti
Pavlenko, Vadim A.
Fritsky, Igor O.
author_sort Seredyuk, Maksym
collection PubMed
description In the title compound, {[Cu(C(10)H(14)N(4)Se)(2)](ClO(4))(2)}(n), the Cu(II) ion is located on a twofold rotation axis and has a tetra­gonally distorted square-planar geometry constituted by four N atoms. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide (L) ligands bridges the copper centers into a polymeric chain extending along [001]. The perchlorate anions are involved in inter­molecular N—H⋯O hydrogen bonding, which links the chains into layers parallel to the bc plane.
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spelling pubmed-29711482010-12-30 catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)] Seredyuk, Maksym Haukka, Matti Pavlenko, Vadim A. Fritsky, Igor O. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(10)H(14)N(4)Se)(2)](ClO(4))(2)}(n), the Cu(II) ion is located on a twofold rotation axis and has a tetra­gonally distorted square-planar geometry constituted by four N atoms. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide (L) ligands bridges the copper centers into a polymeric chain extending along [001]. The perchlorate anions are involved in inter­molecular N—H⋯O hydrogen bonding, which links the chains into layers parallel to the bc plane. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971148/ /pubmed/21578140 http://dx.doi.org/10.1107/S1600536809042056 Text en © Seredyuk et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Seredyuk, Maksym
Haukka, Matti
Pavlenko, Vadim A.
Fritsky, Igor O.
catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title_full catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title_fullStr catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title_full_unstemmed catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title_short catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title_sort catena-poly[[copper(ii)-bis[μ-bis(3,5-dimethyl-1h-pyrazol-4-yl) selenide]] bis(perchlorate)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971148/
https://www.ncbi.nlm.nih.gov/pubmed/21578140
http://dx.doi.org/10.1107/S1600536809042056
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