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Ethyl­enediammonium tetraaquadi­sulfatomagnesium(II)

The title compound, [NH(3)(CH(2))(2)NH(3)][Mg(SO(4))(2)(H(2)O)(4)], was synthesized by the slow evaporation method. Its crystal structure can be described as an alternate stacking of inorganic layers of tetra­aqua­bis(sulfato-O)magnesium [Mg(SO(4))(2)(H(2)O)(4)](2−) anions ([Image: see text] symmetr...

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Detalles Bibliográficos
Autores principales: Rekik, Walid, Naïli, Houcine, Mhiri, Tahar, Bataille, Thierry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971149/
https://www.ncbi.nlm.nih.gov/pubmed/21578145
http://dx.doi.org/10.1107/S1600536809041981
Descripción
Sumario:The title compound, [NH(3)(CH(2))(2)NH(3)][Mg(SO(4))(2)(H(2)O)(4)], was synthesized by the slow evaporation method. Its crystal structure can be described as an alternate stacking of inorganic layers of tetra­aqua­bis(sulfato-O)magnesium [Mg(SO(4))(2)(H(2)O)(4)](2−) anions ([Image: see text] symmetry) and organic layers of [NH(3)(CH(2))(2)NH(3)](2+) cations along the crystallographic b axis. The anions, built up from tetrahedral SO(4) units and octahedral Mg(H(2)O)(4)O(2) units, and the cations are linked together through N—H⋯O hydrogen bonds, forming a three-dimensional network. O—H⋯O inter­actions are also present.