Ethyl­enediammonium tetraaquadi­sulfatomagnesium(II)

The title compound, [NH(3)(CH(2))(2)NH(3)][Mg(SO(4))(2)(H(2)O)(4)], was synthesized by the slow evaporation method. Its crystal structure can be described as an alternate stacking of inorganic layers of tetra­aqua­bis(sulfato-O)magnesium [Mg(SO(4))(2)(H(2)O)(4)](2−) anions ([Image: see text] symmetr...

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Detalles Bibliográficos
Autores principales: Rekik, Walid, Naïli, Houcine, Mhiri, Tahar, Bataille, Thierry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971149/
https://www.ncbi.nlm.nih.gov/pubmed/21578145
http://dx.doi.org/10.1107/S1600536809041981
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author Rekik, Walid
Naïli, Houcine
Mhiri, Tahar
Bataille, Thierry
author_facet Rekik, Walid
Naïli, Houcine
Mhiri, Tahar
Bataille, Thierry
author_sort Rekik, Walid
collection PubMed
description The title compound, [NH(3)(CH(2))(2)NH(3)][Mg(SO(4))(2)(H(2)O)(4)], was synthesized by the slow evaporation method. Its crystal structure can be described as an alternate stacking of inorganic layers of tetra­aqua­bis(sulfato-O)magnesium [Mg(SO(4))(2)(H(2)O)(4)](2−) anions ([Image: see text] symmetry) and organic layers of [NH(3)(CH(2))(2)NH(3)](2+) cations along the crystallographic b axis. The anions, built up from tetrahedral SO(4) units and octahedral Mg(H(2)O)(4)O(2) units, and the cations are linked together through N—H⋯O hydrogen bonds, forming a three-dimensional network. O—H⋯O inter­actions are also present.
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spelling pubmed-29711492010-12-30 Ethyl­enediammonium tetraaquadi­sulfatomagnesium(II) Rekik, Walid Naïli, Houcine Mhiri, Tahar Bataille, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [NH(3)(CH(2))(2)NH(3)][Mg(SO(4))(2)(H(2)O)(4)], was synthesized by the slow evaporation method. Its crystal structure can be described as an alternate stacking of inorganic layers of tetra­aqua­bis(sulfato-O)magnesium [Mg(SO(4))(2)(H(2)O)(4)](2−) anions ([Image: see text] symmetry) and organic layers of [NH(3)(CH(2))(2)NH(3)](2+) cations along the crystallographic b axis. The anions, built up from tetrahedral SO(4) units and octahedral Mg(H(2)O)(4)O(2) units, and the cations are linked together through N—H⋯O hydrogen bonds, forming a three-dimensional network. O—H⋯O inter­actions are also present. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971149/ /pubmed/21578145 http://dx.doi.org/10.1107/S1600536809041981 Text en © Rekik et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rekik, Walid
Naïli, Houcine
Mhiri, Tahar
Bataille, Thierry
Ethyl­enediammonium tetraaquadi­sulfatomagnesium(II)
title Ethyl­enediammonium tetraaquadi­sulfatomagnesium(II)
title_full Ethyl­enediammonium tetraaquadi­sulfatomagnesium(II)
title_fullStr Ethyl­enediammonium tetraaquadi­sulfatomagnesium(II)
title_full_unstemmed Ethyl­enediammonium tetraaquadi­sulfatomagnesium(II)
title_short Ethyl­enediammonium tetraaquadi­sulfatomagnesium(II)
title_sort ethyl­enediammonium tetraaquadi­sulfatomagnesium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971149/
https://www.ncbi.nlm.nih.gov/pubmed/21578145
http://dx.doi.org/10.1107/S1600536809041981
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AT nailihoucine ethylenediammoniumtetraaquadisulfatomagnesiumii
AT mhiritahar ethylenediammoniumtetraaquadisulfatomagnesiumii
AT bataillethierry ethylenediammoniumtetraaquadisulfatomagnesiumii

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