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Bis[2-(benzimidazol-2-ylsulfanyl)acetato]bis(2,2′-bipyridine)cadmium(II)
In the structure of the title compound, [Cd(C(9)H(7)N(2)O(2)S)(2)(C(10)H(8)N(2))(2)], the complex molecules are located on a crystallographic twofold rotation axis and the Cd(II) ion is octahedrally coordinated by two chelating 2,2′-bipyridine ligands and two O atoms from the carboxylate groups o...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971152/ https://www.ncbi.nlm.nih.gov/pubmed/21578110 http://dx.doi.org/10.1107/S1600536809039592 |
Sumario: | In the structure of the title compound, [Cd(C(9)H(7)N(2)O(2)S)(2)(C(10)H(8)N(2))(2)], the complex molecules are located on a crystallographic twofold rotation axis and the Cd(II) ion is octahedrally coordinated by two chelating 2,2′-bipyridine ligands and two O atoms from the carboxylate groups of two 2-(benzimidazol-2-ylsulfanyl)acetate ligands. The two carboxylate ligands adopt a cis configuration with respect to each other. Within each of these ligands, the imidazole fragments are bent back in a loop towards the acetyl groups, forming intramolecular N—H⋯O hydrogen bonds, which help to stablilize the mononuclear complex. Adjacent molecules are further linked by weak C—H⋯O hydrogen bonds, resulting in a chain along the c axis. |
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