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Bis[2-(benzimidazol-2-ylsulfanyl)acetato]bis(2,2′-bipyridine)cadmium(II)
In the structure of the title compound, [Cd(C(9)H(7)N(2)O(2)S)(2)(C(10)H(8)N(2))(2)], the complex molecules are located on a crystallographic twofold rotation axis and the Cd(II) ion is octahedrally coordinated by two chelating 2,2′-bipyridine ligands and two O atoms from the carboxylate groups o...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971152/ https://www.ncbi.nlm.nih.gov/pubmed/21578110 http://dx.doi.org/10.1107/S1600536809039592 |
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author | Cheng, Lin Sun, Yan-Yan Wang, Jian-Quan Zhang, Ya-Wen |
author_facet | Cheng, Lin Sun, Yan-Yan Wang, Jian-Quan Zhang, Ya-Wen |
author_sort | Cheng, Lin |
collection | PubMed |
description | In the structure of the title compound, [Cd(C(9)H(7)N(2)O(2)S)(2)(C(10)H(8)N(2))(2)], the complex molecules are located on a crystallographic twofold rotation axis and the Cd(II) ion is octahedrally coordinated by two chelating 2,2′-bipyridine ligands and two O atoms from the carboxylate groups of two 2-(benzimidazol-2-ylsulfanyl)acetate ligands. The two carboxylate ligands adopt a cis configuration with respect to each other. Within each of these ligands, the imidazole fragments are bent back in a loop towards the acetyl groups, forming intramolecular N—H⋯O hydrogen bonds, which help to stablilize the mononuclear complex. Adjacent molecules are further linked by weak C—H⋯O hydrogen bonds, resulting in a chain along the c axis. |
format | Text |
id | pubmed-2971152 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29711522010-12-30 Bis[2-(benzimidazol-2-ylsulfanyl)acetato]bis(2,2′-bipyridine)cadmium(II) Cheng, Lin Sun, Yan-Yan Wang, Jian-Quan Zhang, Ya-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Cd(C(9)H(7)N(2)O(2)S)(2)(C(10)H(8)N(2))(2)], the complex molecules are located on a crystallographic twofold rotation axis and the Cd(II) ion is octahedrally coordinated by two chelating 2,2′-bipyridine ligands and two O atoms from the carboxylate groups of two 2-(benzimidazol-2-ylsulfanyl)acetate ligands. The two carboxylate ligands adopt a cis configuration with respect to each other. Within each of these ligands, the imidazole fragments are bent back in a loop towards the acetyl groups, forming intramolecular N—H⋯O hydrogen bonds, which help to stablilize the mononuclear complex. Adjacent molecules are further linked by weak C—H⋯O hydrogen bonds, resulting in a chain along the c axis. International Union of Crystallography 2009-10-13 /pmc/articles/PMC2971152/ /pubmed/21578110 http://dx.doi.org/10.1107/S1600536809039592 Text en © Cheng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cheng, Lin Sun, Yan-Yan Wang, Jian-Quan Zhang, Ya-Wen Bis[2-(benzimidazol-2-ylsulfanyl)acetato]bis(2,2′-bipyridine)cadmium(II) |
title | Bis[2-(benzimidazol-2-ylsulfanyl)acetato]bis(2,2′-bipyridine)cadmium(II) |
title_full | Bis[2-(benzimidazol-2-ylsulfanyl)acetato]bis(2,2′-bipyridine)cadmium(II) |
title_fullStr | Bis[2-(benzimidazol-2-ylsulfanyl)acetato]bis(2,2′-bipyridine)cadmium(II) |
title_full_unstemmed | Bis[2-(benzimidazol-2-ylsulfanyl)acetato]bis(2,2′-bipyridine)cadmium(II) |
title_short | Bis[2-(benzimidazol-2-ylsulfanyl)acetato]bis(2,2′-bipyridine)cadmium(II) |
title_sort | bis[2-(benzimidazol-2-ylsulfanyl)acetato]bis(2,2′-bipyridine)cadmium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971152/ https://www.ncbi.nlm.nih.gov/pubmed/21578110 http://dx.doi.org/10.1107/S1600536809039592 |
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