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Bis[2-(benzimidazol-2-ylsulfan­yl)acetato]bis­(2,2′-bipyridine)cadmium(II)

In the structure of the title compound, [Cd(C(9)H(7)N(2)O(2)S)(2)(C(10)H(8)N(2))(2)], the complex mol­ecules are located on a crystallographic twofold rotation axis and the Cd(II) ion is octa­hedrally coordinated by two chelating 2,2′-bipyridine ligands and two O atoms from the carboxyl­ate groups o...

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Detalles Bibliográficos
Autores principales: Cheng, Lin, Sun, Yan-Yan, Wang, Jian-Quan, Zhang, Ya-Wen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971152/
https://www.ncbi.nlm.nih.gov/pubmed/21578110
http://dx.doi.org/10.1107/S1600536809039592
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author Cheng, Lin
Sun, Yan-Yan
Wang, Jian-Quan
Zhang, Ya-Wen
author_facet Cheng, Lin
Sun, Yan-Yan
Wang, Jian-Quan
Zhang, Ya-Wen
author_sort Cheng, Lin
collection PubMed
description In the structure of the title compound, [Cd(C(9)H(7)N(2)O(2)S)(2)(C(10)H(8)N(2))(2)], the complex mol­ecules are located on a crystallographic twofold rotation axis and the Cd(II) ion is octa­hedrally coordinated by two chelating 2,2′-bipyridine ligands and two O atoms from the carboxyl­ate groups of two 2-(benzimidazol-2-ylsulfan­yl)acetate ligands. The two carboxyl­ate ligands adopt a cis configuration with respect to each other. Within each of these ligands, the imidazole fragments are bent back in a loop towards the acetyl groups, forming intra­molecular N—H⋯O hydrogen bonds, which help to stablilize the mononuclear complex. Adjacent mol­ecules are further linked by weak C—H⋯O hydrogen bonds, resulting in a chain along the c axis.
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spelling pubmed-29711522010-12-30 Bis[2-(benzimidazol-2-ylsulfan­yl)acetato]bis­(2,2′-bipyridine)cadmium(II) Cheng, Lin Sun, Yan-Yan Wang, Jian-Quan Zhang, Ya-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Cd(C(9)H(7)N(2)O(2)S)(2)(C(10)H(8)N(2))(2)], the complex mol­ecules are located on a crystallographic twofold rotation axis and the Cd(II) ion is octa­hedrally coordinated by two chelating 2,2′-bipyridine ligands and two O atoms from the carboxyl­ate groups of two 2-(benzimidazol-2-ylsulfan­yl)acetate ligands. The two carboxyl­ate ligands adopt a cis configuration with respect to each other. Within each of these ligands, the imidazole fragments are bent back in a loop towards the acetyl groups, forming intra­molecular N—H⋯O hydrogen bonds, which help to stablilize the mononuclear complex. Adjacent mol­ecules are further linked by weak C—H⋯O hydrogen bonds, resulting in a chain along the c axis. International Union of Crystallography 2009-10-13 /pmc/articles/PMC2971152/ /pubmed/21578110 http://dx.doi.org/10.1107/S1600536809039592 Text en © Cheng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Lin
Sun, Yan-Yan
Wang, Jian-Quan
Zhang, Ya-Wen
Bis[2-(benzimidazol-2-ylsulfan­yl)acetato]bis­(2,2′-bipyridine)cadmium(II)
title Bis[2-(benzimidazol-2-ylsulfan­yl)acetato]bis­(2,2′-bipyridine)cadmium(II)
title_full Bis[2-(benzimidazol-2-ylsulfan­yl)acetato]bis­(2,2′-bipyridine)cadmium(II)
title_fullStr Bis[2-(benzimidazol-2-ylsulfan­yl)acetato]bis­(2,2′-bipyridine)cadmium(II)
title_full_unstemmed Bis[2-(benzimidazol-2-ylsulfan­yl)acetato]bis­(2,2′-bipyridine)cadmium(II)
title_short Bis[2-(benzimidazol-2-ylsulfan­yl)acetato]bis­(2,2′-bipyridine)cadmium(II)
title_sort bis[2-(benzimidazol-2-ylsulfan­yl)acetato]bis­(2,2′-bipyridine)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971152/
https://www.ncbi.nlm.nih.gov/pubmed/21578110
http://dx.doi.org/10.1107/S1600536809039592
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