Poly[[bis­(μ(2)-6-methyl­pyrazin-2-carboxyl­ato-κ(3) N (1),O:N (4))copper(II)] dihydrate]

In the title compound, {[Cu(C(6)H(5)N(2)O(2))(2)]·2H(2)O}(n), the Cu(II) ion (site symmetry [Image: see text]) is coordinated by two N,O-bidentate ligands and two N-monodentate ligands in a distorted CuO(2)N(4) octa­hedral geometry. Each anion acts as a bridge between two cations, thus forming a two...

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Detalles Bibliográficos
Autores principales: Fan, Chuan-gang, Wei, Xin-Ting, Li, Linwei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971155/
https://www.ncbi.nlm.nih.gov/pubmed/21578150
http://dx.doi.org/10.1107/S1600536809041440
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author Fan, Chuan-gang
Wei, Xin-Ting
Li, Linwei
author_facet Fan, Chuan-gang
Wei, Xin-Ting
Li, Linwei
author_sort Fan, Chuan-gang
collection PubMed
description In the title compound, {[Cu(C(6)H(5)N(2)O(2))(2)]·2H(2)O}(n), the Cu(II) ion (site symmetry [Image: see text]) is coordinated by two N,O-bidentate ligands and two N-monodentate ligands in a distorted CuO(2)N(4) octa­hedral geometry. Each anion acts as a bridge between two cations, thus forming a two-dimensional polymeric network parallel to the ab plane. The packing is consolidated by O—H⋯O hydrogen bonds. One of the O atoms of the ligand and both water mol­ecules are disordered.
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spelling pubmed-29711552010-12-30 Poly[[bis­(μ(2)-6-methyl­pyrazin-2-carboxyl­ato-κ(3) N (1),O:N (4))copper(II)] dihydrate] Fan, Chuan-gang Wei, Xin-Ting Li, Linwei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(6)H(5)N(2)O(2))(2)]·2H(2)O}(n), the Cu(II) ion (site symmetry [Image: see text]) is coordinated by two N,O-bidentate ligands and two N-monodentate ligands in a distorted CuO(2)N(4) octa­hedral geometry. Each anion acts as a bridge between two cations, thus forming a two-dimensional polymeric network parallel to the ab plane. The packing is consolidated by O—H⋯O hydrogen bonds. One of the O atoms of the ligand and both water mol­ecules are disordered. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971155/ /pubmed/21578150 http://dx.doi.org/10.1107/S1600536809041440 Text en © Fan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Chuan-gang
Wei, Xin-Ting
Li, Linwei
Poly[[bis­(μ(2)-6-methyl­pyrazin-2-carboxyl­ato-κ(3) N (1),O:N (4))copper(II)] dihydrate]
title Poly[[bis­(μ(2)-6-methyl­pyrazin-2-carboxyl­ato-κ(3) N (1),O:N (4))copper(II)] dihydrate]
title_full Poly[[bis­(μ(2)-6-methyl­pyrazin-2-carboxyl­ato-κ(3) N (1),O:N (4))copper(II)] dihydrate]
title_fullStr Poly[[bis­(μ(2)-6-methyl­pyrazin-2-carboxyl­ato-κ(3) N (1),O:N (4))copper(II)] dihydrate]
title_full_unstemmed Poly[[bis­(μ(2)-6-methyl­pyrazin-2-carboxyl­ato-κ(3) N (1),O:N (4))copper(II)] dihydrate]
title_short Poly[[bis­(μ(2)-6-methyl­pyrazin-2-carboxyl­ato-κ(3) N (1),O:N (4))copper(II)] dihydrate]
title_sort poly[[bis­(μ(2)-6-methyl­pyrazin-2-carboxyl­ato-κ(3) n (1),o:n (4))copper(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971155/
https://www.ncbi.nlm.nih.gov/pubmed/21578150
http://dx.doi.org/10.1107/S1600536809041440
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