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Ethyl 2-(4-benzoyl-2,5-dimethyl­phen­oxy)acetate

The title compound, C(19)H(20)O(4), was synthesized via a Fries rearrangement of hydr­oxy benzophenone. The dihedral angle between the least-squares planes of the two benzene rings is 69.04 (11)°. The mol­ecular structure displays an intra­molecular non-classical C—H⋯O hydrogen bond.

Detalles Bibliográficos
Autores principales: Devarajegowda, H. C., Khanum, Shaukath Ara, Jeyaseelan, S., Eryani, Waleed Al, Shylajakumari, J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971156/
https://www.ncbi.nlm.nih.gov/pubmed/21578443
http://dx.doi.org/10.1107/S1600536809043190
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author Devarajegowda, H. C.
Khanum, Shaukath Ara
Jeyaseelan, S.
Eryani, Waleed Al
Shylajakumari, J.
author_facet Devarajegowda, H. C.
Khanum, Shaukath Ara
Jeyaseelan, S.
Eryani, Waleed Al
Shylajakumari, J.
author_sort Devarajegowda, H. C.
collection PubMed
description The title compound, C(19)H(20)O(4), was synthesized via a Fries rearrangement of hydr­oxy benzophenone. The dihedral angle between the least-squares planes of the two benzene rings is 69.04 (11)°. The mol­ecular structure displays an intra­molecular non-classical C—H⋯O hydrogen bond.
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spelling pubmed-29711562010-12-30 Ethyl 2-(4-benzoyl-2,5-dimethyl­phen­oxy)acetate Devarajegowda, H. C. Khanum, Shaukath Ara Jeyaseelan, S. Eryani, Waleed Al Shylajakumari, J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(20)O(4), was synthesized via a Fries rearrangement of hydr­oxy benzophenone. The dihedral angle between the least-squares planes of the two benzene rings is 69.04 (11)°. The mol­ecular structure displays an intra­molecular non-classical C—H⋯O hydrogen bond. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971156/ /pubmed/21578443 http://dx.doi.org/10.1107/S1600536809043190 Text en © Devarajegowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Devarajegowda, H. C.
Khanum, Shaukath Ara
Jeyaseelan, S.
Eryani, Waleed Al
Shylajakumari, J.
Ethyl 2-(4-benzoyl-2,5-dimethyl­phen­oxy)acetate
title Ethyl 2-(4-benzoyl-2,5-dimethyl­phen­oxy)acetate
title_full Ethyl 2-(4-benzoyl-2,5-dimethyl­phen­oxy)acetate
title_fullStr Ethyl 2-(4-benzoyl-2,5-dimethyl­phen­oxy)acetate
title_full_unstemmed Ethyl 2-(4-benzoyl-2,5-dimethyl­phen­oxy)acetate
title_short Ethyl 2-(4-benzoyl-2,5-dimethyl­phen­oxy)acetate
title_sort ethyl 2-(4-benzoyl-2,5-dimethyl­phen­oxy)acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971156/
https://www.ncbi.nlm.nih.gov/pubmed/21578443
http://dx.doi.org/10.1107/S1600536809043190
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AT khanumshaukathara ethyl24benzoyl25dimethylphenoxyacetate
AT jeyaseelans ethyl24benzoyl25dimethylphenoxyacetate
AT eryaniwaleedal ethyl24benzoyl25dimethylphenoxyacetate
AT shylajakumarij ethyl24benzoyl25dimethylphenoxyacetate