1-Chloro­acetyl-r-2,c-6-bis­(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one

In the title compound, C(23)H(26)ClNO(4), the piperidine ring adopts a distorted boat conformation. The two methoxy­phenyl groups at the 2 and 6 positions of the piperidine ring are in axial and equatorial orientations. An intra­molecular C—H⋯Cl inter­action is observed. In the crystal, the mol­ecul...

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Detalles Bibliográficos
Autores principales: Thenmozhi, M., Kavitha, T., Mohanraj, V., Ponnuswamy, S., Ponnuswamy, M. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971163/
https://www.ncbi.nlm.nih.gov/pubmed/21578385
http://dx.doi.org/10.1107/S1600536809041555
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author Thenmozhi, M.
Kavitha, T.
Mohanraj, V.
Ponnuswamy, S.
Ponnuswamy, M. N.
author_facet Thenmozhi, M.
Kavitha, T.
Mohanraj, V.
Ponnuswamy, S.
Ponnuswamy, M. N.
author_sort Thenmozhi, M.
collection PubMed
description In the title compound, C(23)H(26)ClNO(4), the piperidine ring adopts a distorted boat conformation. The two methoxy­phenyl groups at the 2 and 6 positions of the piperidine ring are in axial and equatorial orientations. An intra­molecular C—H⋯Cl inter­action is observed. In the crystal, the mol­ecules are linked into zigzag chains along the b axis by C—H⋯π inter­molecular inter­actions.
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spelling pubmed-29711632010-12-30 1-Chloro­acetyl-r-2,c-6-bis­(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one Thenmozhi, M. Kavitha, T. Mohanraj, V. Ponnuswamy, S. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(26)ClNO(4), the piperidine ring adopts a distorted boat conformation. The two methoxy­phenyl groups at the 2 and 6 positions of the piperidine ring are in axial and equatorial orientations. An intra­molecular C—H⋯Cl inter­action is observed. In the crystal, the mol­ecules are linked into zigzag chains along the b axis by C—H⋯π inter­molecular inter­actions. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971163/ /pubmed/21578385 http://dx.doi.org/10.1107/S1600536809041555 Text en © Thenmozhi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thenmozhi, M.
Kavitha, T.
Mohanraj, V.
Ponnuswamy, S.
Ponnuswamy, M. N.
1-Chloro­acetyl-r-2,c-6-bis­(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title 1-Chloro­acetyl-r-2,c-6-bis­(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title_full 1-Chloro­acetyl-r-2,c-6-bis­(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title_fullStr 1-Chloro­acetyl-r-2,c-6-bis­(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title_full_unstemmed 1-Chloro­acetyl-r-2,c-6-bis­(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title_short 1-Chloro­acetyl-r-2,c-6-bis­(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title_sort 1-chloro­acetyl-r-2,c-6-bis­(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971163/
https://www.ncbi.nlm.nih.gov/pubmed/21578385
http://dx.doi.org/10.1107/S1600536809041555
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