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Bis[μ-1-(2-pyridylmethyl)-1H-benzotriazole]disilver(I) bis(perchlorate)
In the title centrosymmetric binuclear Ag(I )complex, [Ag(2)(C(12)H(10)N(4))(2)](ClO(4))(2), each Ag(I) center is two-coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 1-(2-pyridylmethyl)-1H-benzotriazole (L) ligands. This forms a unique box-like cyclic dimer w...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971172/ https://www.ncbi.nlm.nih.gov/pubmed/21578182 http://dx.doi.org/10.1107/S1600536809043669 |
Sumario: | In the title centrosymmetric binuclear Ag(I )complex, [Ag(2)(C(12)H(10)N(4))(2)](ClO(4))(2), each Ag(I) center is two-coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 1-(2-pyridylmethyl)-1H-benzotriazole (L) ligands. This forms a unique box-like cyclic dimer with an intramolecular Ag⋯Ag separation of 4.479 (2) Å. Intermolecular C—H⋯O hydrogen-bonding interactions, involving uncoordinated ClO(4) (−) ions, link the binuclear units, forming a two-dimensional network parallel to (10[Image: see text]). |
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