Bis[μ-1-(2-pyridylmeth­yl)-1H-benzo­triazole]disilver(I) bis­(perchlorate)

In the title centrosymmetric binuclear Ag(I )complex, [Ag(2)(C(12)H(10)N(4))(2)](ClO(4))(2), each Ag(I) center is two-coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 1-(2-pyridylmeth­yl)-1H-benzotriazole (L) ligands. This forms a unique box-like cyclic dimer w...

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Detalles Bibliográficos
Autores principales: Liu, Chun-Sen, Xiao, Xian-Guo, Hu, Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971172/
https://www.ncbi.nlm.nih.gov/pubmed/21578182
http://dx.doi.org/10.1107/S1600536809043669
Descripción
Sumario:In the title centrosymmetric binuclear Ag(I )complex, [Ag(2)(C(12)H(10)N(4))(2)](ClO(4))(2), each Ag(I) center is two-coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 1-(2-pyridylmeth­yl)-1H-benzotriazole (L) ligands. This forms a unique box-like cyclic dimer with an intra­molecular Ag⋯Ag separation of 4.479 (2) Å. Inter­molecular C—H⋯O hydrogen-bonding inter­actions, involving uncoordinated ClO(4) (−) ions, link the binuclear units, forming a two-dimensional network parallel to (10[Image: see text]).

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