Bis[μ-1-(2-pyridylmeth­yl)-1H-benzo­triazole]disilver(I) bis­(perchlorate)

In the title centrosymmetric binuclear Ag(I )complex, [Ag(2)(C(12)H(10)N(4))(2)](ClO(4))(2), each Ag(I) center is two-coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 1-(2-pyridylmeth­yl)-1H-benzotriazole (L) ligands. This forms a unique box-like cyclic dimer w...

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Detalles Bibliográficos
Autores principales: Liu, Chun-Sen, Xiao, Xian-Guo, Hu, Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971172/
https://www.ncbi.nlm.nih.gov/pubmed/21578182
http://dx.doi.org/10.1107/S1600536809043669
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author Liu, Chun-Sen
Xiao, Xian-Guo
Hu, Min
author_facet Liu, Chun-Sen
Xiao, Xian-Guo
Hu, Min
author_sort Liu, Chun-Sen
collection PubMed
description In the title centrosymmetric binuclear Ag(I )complex, [Ag(2)(C(12)H(10)N(4))(2)](ClO(4))(2), each Ag(I) center is two-coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 1-(2-pyridylmeth­yl)-1H-benzotriazole (L) ligands. This forms a unique box-like cyclic dimer with an intra­molecular Ag⋯Ag separation of 4.479 (2) Å. Inter­molecular C—H⋯O hydrogen-bonding inter­actions, involving uncoordinated ClO(4) (−) ions, link the binuclear units, forming a two-dimensional network parallel to (10[Image: see text]).
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spelling pubmed-29711722010-12-30 Bis[μ-1-(2-pyridylmeth­yl)-1H-benzo­triazole]disilver(I) bis­(perchlorate) Liu, Chun-Sen Xiao, Xian-Guo Hu, Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric binuclear Ag(I )complex, [Ag(2)(C(12)H(10)N(4))(2)](ClO(4))(2), each Ag(I) center is two-coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 1-(2-pyridylmeth­yl)-1H-benzotriazole (L) ligands. This forms a unique box-like cyclic dimer with an intra­molecular Ag⋯Ag separation of 4.479 (2) Å. Inter­molecular C—H⋯O hydrogen-bonding inter­actions, involving uncoordinated ClO(4) (−) ions, link the binuclear units, forming a two-dimensional network parallel to (10[Image: see text]). International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971172/ /pubmed/21578182 http://dx.doi.org/10.1107/S1600536809043669 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Chun-Sen
Xiao, Xian-Guo
Hu, Min
Bis[μ-1-(2-pyridylmeth­yl)-1H-benzo­triazole]disilver(I) bis­(perchlorate)
title Bis[μ-1-(2-pyridylmeth­yl)-1H-benzo­triazole]disilver(I) bis­(perchlorate)
title_full Bis[μ-1-(2-pyridylmeth­yl)-1H-benzo­triazole]disilver(I) bis­(perchlorate)
title_fullStr Bis[μ-1-(2-pyridylmeth­yl)-1H-benzo­triazole]disilver(I) bis­(perchlorate)
title_full_unstemmed Bis[μ-1-(2-pyridylmeth­yl)-1H-benzo­triazole]disilver(I) bis­(perchlorate)
title_short Bis[μ-1-(2-pyridylmeth­yl)-1H-benzo­triazole]disilver(I) bis­(perchlorate)
title_sort bis[μ-1-(2-pyridylmeth­yl)-1h-benzo­triazole]disilver(i) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971172/
https://www.ncbi.nlm.nih.gov/pubmed/21578182
http://dx.doi.org/10.1107/S1600536809043669
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