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(μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] chloro­form solvate

The dinuclear title solvate, [Zn(2)(C(5)H(10)NS(2))(4)(C(12)H(10)N(2))]·CHCl(3), features two five-coordinate Zn atoms; both coordination polyhedra are distorted, but one has an NS(4) donor set approximating to a square pyramid (with the N atom in the apical site), while the other is closer to a ZnN...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971174/
https://www.ncbi.nlm.nih.gov/pubmed/21578196
http://dx.doi.org/10.1107/S1600536809044237
Descripción
Sumario:The dinuclear title solvate, [Zn(2)(C(5)H(10)NS(2))(4)(C(12)H(10)N(2))]·CHCl(3), features two five-coordinate Zn atoms; both coordination polyhedra are distorted, but one has an NS(4) donor set approximating to a square pyramid (with the N atom in the apical site), while the other is closer to a ZnNS(4) trigonal-bipyramidal arrangement (with the N atom in an equatorial site). In both cases, the Zn(II) atom is chelated by two S,S′-bidentate dithiol­ate ligands. In the crystal, the chloro­form solvent mol­ecules reside in cavities defined by the dinuclear species and are held in place via C—H⋯S contacts.