(μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] chloro­form solvate

The dinuclear title solvate, [Zn(2)(C(5)H(10)NS(2))(4)(C(12)H(10)N(2))]·CHCl(3), features two five-coordinate Zn atoms; both coordination polyhedra are distorted, but one has an NS(4) donor set approximating to a square pyramid (with the N atom in the apical site), while the other is closer to a ZnN...

Descripción completa

Detalles Bibliográficos
Autores principales: Arman, Hadi D., Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971174/
https://www.ncbi.nlm.nih.gov/pubmed/21578196
http://dx.doi.org/10.1107/S1600536809044237
_version_ 1782190563652534272
author Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The dinuclear title solvate, [Zn(2)(C(5)H(10)NS(2))(4)(C(12)H(10)N(2))]·CHCl(3), features two five-coordinate Zn atoms; both coordination polyhedra are distorted, but one has an NS(4) donor set approximating to a square pyramid (with the N atom in the apical site), while the other is closer to a ZnNS(4) trigonal-bipyramidal arrangement (with the N atom in an equatorial site). In both cases, the Zn(II) atom is chelated by two S,S′-bidentate dithiol­ate ligands. In the crystal, the chloro­form solvent mol­ecules reside in cavities defined by the dinuclear species and are held in place via C—H⋯S contacts.
format Text
id pubmed-2971174
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29711742010-12-30 (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] chloro­form solvate Arman, Hadi D. Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title solvate, [Zn(2)(C(5)H(10)NS(2))(4)(C(12)H(10)N(2))]·CHCl(3), features two five-coordinate Zn atoms; both coordination polyhedra are distorted, but one has an NS(4) donor set approximating to a square pyramid (with the N atom in the apical site), while the other is closer to a ZnNS(4) trigonal-bipyramidal arrangement (with the N atom in an equatorial site). In both cases, the Zn(II) atom is chelated by two S,S′-bidentate dithiol­ate ligands. In the crystal, the chloro­form solvent mol­ecules reside in cavities defined by the dinuclear species and are held in place via C—H⋯S contacts. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971174/ /pubmed/21578196 http://dx.doi.org/10.1107/S1600536809044237 Text en © Arman et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
(μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] chloro­form solvate
title (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] chloro­form solvate
title_full (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] chloro­form solvate
title_fullStr (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] chloro­form solvate
title_full_unstemmed (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] chloro­form solvate
title_short (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] chloro­form solvate
title_sort (μ-trans-1,2-di-4-pyridylethyl­ene-κ(2) n:n′)bis­[bis­(n,n-diethyl­dithio­carbamato-κ(2) s,s′)zinc(ii)] chloro­form solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971174/
https://www.ncbi.nlm.nih.gov/pubmed/21578196
http://dx.doi.org/10.1107/S1600536809044237
work_keys_str_mv AT armanhadid mtrans12di4pyridylethylenek2nnbisbisnndiethyldithiocarbamatok2sszinciichloroformsolvate
AT poplaukhinpavel mtrans12di4pyridylethylenek2nnbisbisnndiethyldithiocarbamatok2sszinciichloroformsolvate
AT tiekinkedwardrt mtrans12di4pyridylethylenek2nnbisbisnndiethyldithiocarbamatok2sszinciichloroformsolvate

Ejemplares similares