catena-Poly[[bis­(O,O′-diisopropyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-bis­(4-pyridylmethyl­ene)diazane-κ(2) N:N′]

The Ni atom in the title linear supra­molecular polymer, [Ni(C(6)H(14)O(2)PS(2))(2)(C(12)H(10)N(4))](n), exists within a trans-N(2)S(4) octa­hedral donor set defined by two symmetrically coordinating dithio­phosphate ligands and pyridine N atoms derived from two bridging bis­(4-pyridylmethyl­ene)dia...

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Detalles Bibliográficos
Autores principales: Berdugo, Erick, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971175/
https://www.ncbi.nlm.nih.gov/pubmed/21578175
http://dx.doi.org/10.1107/S1600536809043505
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author Berdugo, Erick
Tiekink, Edward R. T.
author_facet Berdugo, Erick
Tiekink, Edward R. T.
author_sort Berdugo, Erick
collection PubMed
description The Ni atom in the title linear supra­molecular polymer, [Ni(C(6)H(14)O(2)PS(2))(2)(C(12)H(10)N(4))](n), exists within a trans-N(2)S(4) octa­hedral donor set defined by two symmetrically coordinating dithio­phosphate ligands and pyridine N atoms derived from two bridging bis­(4-pyridylmethyl­ene)diazane ligands. The Ni atom lies on a centre of inversion and the bis­(4-pyridylmethyl­ene)diazane ligand is also disposed about a centre of inversion. The chains are arranged into layers sustained by C—H⋯S contacts and inter­digitate with neighbouring layers, forming the crystal structure.
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spelling pubmed-29711752010-12-30 catena-Poly[[bis­(O,O′-diisopropyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-bis­(4-pyridylmethyl­ene)diazane-κ(2) N:N′] Berdugo, Erick Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni atom in the title linear supra­molecular polymer, [Ni(C(6)H(14)O(2)PS(2))(2)(C(12)H(10)N(4))](n), exists within a trans-N(2)S(4) octa­hedral donor set defined by two symmetrically coordinating dithio­phosphate ligands and pyridine N atoms derived from two bridging bis­(4-pyridylmethyl­ene)diazane ligands. The Ni atom lies on a centre of inversion and the bis­(4-pyridylmethyl­ene)diazane ligand is also disposed about a centre of inversion. The chains are arranged into layers sustained by C—H⋯S contacts and inter­digitate with neighbouring layers, forming the crystal structure. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971175/ /pubmed/21578175 http://dx.doi.org/10.1107/S1600536809043505 Text en © Berdugo and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Berdugo, Erick
Tiekink, Edward R. T.
catena-Poly[[bis­(O,O′-diisopropyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-bis­(4-pyridylmethyl­ene)diazane-κ(2) N:N′]
title catena-Poly[[bis­(O,O′-diisopropyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-bis­(4-pyridylmethyl­ene)diazane-κ(2) N:N′]
title_full catena-Poly[[bis­(O,O′-diisopropyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-bis­(4-pyridylmethyl­ene)diazane-κ(2) N:N′]
title_fullStr catena-Poly[[bis­(O,O′-diisopropyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-bis­(4-pyridylmethyl­ene)diazane-κ(2) N:N′]
title_full_unstemmed catena-Poly[[bis­(O,O′-diisopropyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-bis­(4-pyridylmethyl­ene)diazane-κ(2) N:N′]
title_short catena-Poly[[bis­(O,O′-diisopropyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-bis­(4-pyridylmethyl­ene)diazane-κ(2) N:N′]
title_sort catena-poly[[bis­(o,o′-diisopropyl dithio­phosphato-κ(2) s,s′)nickel(ii)]-μ-bis­(4-pyridylmethyl­ene)diazane-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971175/
https://www.ncbi.nlm.nih.gov/pubmed/21578175
http://dx.doi.org/10.1107/S1600536809043505
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