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[μ-4-Benzoyl-1-(1-oxido-2-naphthyl­carbon­yl)thio­semicarbazidato(4−)]bis­[pyridine­copper(II)]

In the title dinuclear complex, [Cu(2)(C(19)H(11)N(3)O(3)S)(C(5)H(5)N)(2)], the two Cu(II) centers have different coordination environments, viz. N(2)OS and N(2)O(2), each exhibiting a distorted square-planar geometry. π–π inter­actions between the aromatic rings of neighbouring complexes [centroid–...

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Detalles Bibliográficos
Autores principales: Zhang, Wen, Gao, Jin-Ping, Shi, Xue-Feng, Li, Da-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971176/
https://www.ncbi.nlm.nih.gov/pubmed/21578117
http://dx.doi.org/10.1107/S1600536809040951
Descripción
Sumario:In the title dinuclear complex, [Cu(2)(C(19)H(11)N(3)O(3)S)(C(5)H(5)N)(2)], the two Cu(II) centers have different coordination environments, viz. N(2)OS and N(2)O(2), each exhibiting a distorted square-planar geometry. π–π inter­actions between the aromatic rings of neighbouring complexes [centroid–centroid distance = 3.856 (5) Å] link pairs of mol­ecules into centrosymmetric dimers, which are further packed into stacks along the b axis with relatively short Cu⋯Cu separations of 3.482 (1) Å. Weak inter­molecular C—H⋯N hydrogen bonds help to consolidate the crystal packing.