[μ-4-Benzoyl-1-(1-oxido-2-naphthyl­carbon­yl)thio­semicarbazidato(4−)]bis­[pyridine­copper(II)]

In the title dinuclear complex, [Cu(2)(C(19)H(11)N(3)O(3)S)(C(5)H(5)N)(2)], the two Cu(II) centers have different coordination environments, viz. N(2)OS and N(2)O(2), each exhibiting a distorted square-planar geometry. π–π inter­actions between the aromatic rings of neighbouring complexes [centroid–...

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Detalles Bibliográficos
Autores principales: Zhang, Wen, Gao, Jin-Ping, Shi, Xue-Feng, Li, Da-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971176/
https://www.ncbi.nlm.nih.gov/pubmed/21578117
http://dx.doi.org/10.1107/S1600536809040951
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author Zhang, Wen
Gao, Jin-Ping
Shi, Xue-Feng
Li, Da-Cheng
author_facet Zhang, Wen
Gao, Jin-Ping
Shi, Xue-Feng
Li, Da-Cheng
author_sort Zhang, Wen
collection PubMed
description In the title dinuclear complex, [Cu(2)(C(19)H(11)N(3)O(3)S)(C(5)H(5)N)(2)], the two Cu(II) centers have different coordination environments, viz. N(2)OS and N(2)O(2), each exhibiting a distorted square-planar geometry. π–π inter­actions between the aromatic rings of neighbouring complexes [centroid–centroid distance = 3.856 (5) Å] link pairs of mol­ecules into centrosymmetric dimers, which are further packed into stacks along the b axis with relatively short Cu⋯Cu separations of 3.482 (1) Å. Weak inter­molecular C—H⋯N hydrogen bonds help to consolidate the crystal packing.
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spelling pubmed-29711762010-12-30 [μ-4-Benzoyl-1-(1-oxido-2-naphthyl­carbon­yl)thio­semicarbazidato(4−)]bis­[pyridine­copper(II)] Zhang, Wen Gao, Jin-Ping Shi, Xue-Feng Li, Da-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [Cu(2)(C(19)H(11)N(3)O(3)S)(C(5)H(5)N)(2)], the two Cu(II) centers have different coordination environments, viz. N(2)OS and N(2)O(2), each exhibiting a distorted square-planar geometry. π–π inter­actions between the aromatic rings of neighbouring complexes [centroid–centroid distance = 3.856 (5) Å] link pairs of mol­ecules into centrosymmetric dimers, which are further packed into stacks along the b axis with relatively short Cu⋯Cu separations of 3.482 (1) Å. Weak inter­molecular C—H⋯N hydrogen bonds help to consolidate the crystal packing. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971176/ /pubmed/21578117 http://dx.doi.org/10.1107/S1600536809040951 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Wen
Gao, Jin-Ping
Shi, Xue-Feng
Li, Da-Cheng
[μ-4-Benzoyl-1-(1-oxido-2-naphthyl­carbon­yl)thio­semicarbazidato(4−)]bis­[pyridine­copper(II)]
title [μ-4-Benzoyl-1-(1-oxido-2-naphthyl­carbon­yl)thio­semicarbazidato(4−)]bis­[pyridine­copper(II)]
title_full [μ-4-Benzoyl-1-(1-oxido-2-naphthyl­carbon­yl)thio­semicarbazidato(4−)]bis­[pyridine­copper(II)]
title_fullStr [μ-4-Benzoyl-1-(1-oxido-2-naphthyl­carbon­yl)thio­semicarbazidato(4−)]bis­[pyridine­copper(II)]
title_full_unstemmed [μ-4-Benzoyl-1-(1-oxido-2-naphthyl­carbon­yl)thio­semicarbazidato(4−)]bis­[pyridine­copper(II)]
title_short [μ-4-Benzoyl-1-(1-oxido-2-naphthyl­carbon­yl)thio­semicarbazidato(4−)]bis­[pyridine­copper(II)]
title_sort [μ-4-benzoyl-1-(1-oxido-2-naphthyl­carbon­yl)thio­semicarbazidato(4−)]bis­[pyridine­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971176/
https://www.ncbi.nlm.nih.gov/pubmed/21578117
http://dx.doi.org/10.1107/S1600536809040951
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AT shixuefeng m4benzoyl11oxido2naphthylcarbonylthiosemicarbazidato4bispyridinecopperii
AT lidacheng m4benzoyl11oxido2naphthylcarbonylthiosemicarbazidato4bispyridinecopperii

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