Cargando…
N-{Bis[methyl(phenyl)amino]phosphoryl}-2,2,2-trichloroacetamide
In the asymmetric unit of the crystal structure of the title compound, C(16)H(17)Cl(3)N(3)O(2)P, there are two crystallographically independent molecules, which form dimers via N—H⋯O hydrogen bonding between the N—H group and the P=O group. In the molecular structure, the phosphoryl group is anti...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971180/ https://www.ncbi.nlm.nih.gov/pubmed/21578403 http://dx.doi.org/10.1107/S1600536809042391 |
| _version_ | 1782190565194989568 |
|---|---|
| author | Znovjyak, Kateryna O. Ovchynnikov, Vladimir A. Sliva, Tetyana Yu. Shishkina, Svitlana V. Amirkhanov, Vladimir M. |
| author_facet | Znovjyak, Kateryna O. Ovchynnikov, Vladimir A. Sliva, Tetyana Yu. Shishkina, Svitlana V. Amirkhanov, Vladimir M. |
| author_sort | Znovjyak, Kateryna O. |
| collection | PubMed |
| description | In the asymmetric unit of the crystal structure of the title compound, C(16)H(17)Cl(3)N(3)O(2)P, there are two crystallographically independent molecules, which form dimers via N—H⋯O hydrogen bonding between the N—H group and the P=O group. In the molecular structure, the phosphoryl group is anti to the carbonyl group. The two benzene rings are oriented at dihedral angles of 54.3 (2) and 49.7 (2)° in the two independent molecules. |
| format | Text |
| id | pubmed-2971180 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29711802010-12-30 N-{Bis[methyl(phenyl)amino]phosphoryl}-2,2,2-trichloroacetamide Znovjyak, Kateryna O. Ovchynnikov, Vladimir A. Sliva, Tetyana Yu. Shishkina, Svitlana V. Amirkhanov, Vladimir M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the crystal structure of the title compound, C(16)H(17)Cl(3)N(3)O(2)P, there are two crystallographically independent molecules, which form dimers via N—H⋯O hydrogen bonding between the N—H group and the P=O group. In the molecular structure, the phosphoryl group is anti to the carbonyl group. The two benzene rings are oriented at dihedral angles of 54.3 (2) and 49.7 (2)° in the two independent molecules. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971180/ /pubmed/21578403 http://dx.doi.org/10.1107/S1600536809042391 Text en © Znovjyak et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Znovjyak, Kateryna O. Ovchynnikov, Vladimir A. Sliva, Tetyana Yu. Shishkina, Svitlana V. Amirkhanov, Vladimir M. N-{Bis[methyl(phenyl)amino]phosphoryl}-2,2,2-trichloroacetamide |
| title |
N-{Bis[methyl(phenyl)amino]phosphoryl}-2,2,2-trichloroacetamide |
| title_full |
N-{Bis[methyl(phenyl)amino]phosphoryl}-2,2,2-trichloroacetamide |
| title_fullStr |
N-{Bis[methyl(phenyl)amino]phosphoryl}-2,2,2-trichloroacetamide |
| title_full_unstemmed |
N-{Bis[methyl(phenyl)amino]phosphoryl}-2,2,2-trichloroacetamide |
| title_short |
N-{Bis[methyl(phenyl)amino]phosphoryl}-2,2,2-trichloroacetamide |
| title_sort | n-{bis[methyl(phenyl)amino]phosphoryl}-2,2,2-trichloroacetamide |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971180/ https://www.ncbi.nlm.nih.gov/pubmed/21578403 http://dx.doi.org/10.1107/S1600536809042391 |
| work_keys_str_mv | AT znovjyakkaterynao nbismethylphenylaminophosphoryl222trichloroacetamide AT ovchynnikovvladimira nbismethylphenylaminophosphoryl222trichloroacetamide AT slivatetyanayu nbismethylphenylaminophosphoryl222trichloroacetamide AT shishkinasvitlanav nbismethylphenylaminophosphoryl222trichloroacetamide AT amirkhanovvladimirm nbismethylphenylaminophosphoryl222trichloroacetamide |