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Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]

The mol­ecule of the title binuclear copper(II) complex, [Cu(2)(C(14)H(8)O(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(2)], is bis­ected by a crystallographic twofold axis. Each Cu(II) atom is coordinated in a distorted octa­hedral geometry by three O atoms from two biphen­yl-2,2′-dicarboxyl­ate anions, one aq...

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Detalles Bibliográficos
Autores principales: Dong, Xi-Yan, Xu, Xiao-Jie, Yang, Lei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971185/
https://www.ncbi.nlm.nih.gov/pubmed/21578114
http://dx.doi.org/10.1107/S1600536809040628
Descripción
Sumario:The mol­ecule of the title binuclear copper(II) complex, [Cu(2)(C(14)H(8)O(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(2)], is bis­ected by a crystallographic twofold axis. Each Cu(II) atom is coordinated in a distorted octa­hedral geometry by three O atoms from two biphen­yl-2,2′-dicarboxyl­ate anions, one aqua O atom and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand. Intramolecular O—H⋯O hydrogen bonds between the coordinated water molecules and the carboxylate O atoms are also present.