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Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]
The molecule of the title binuclear copper(II) complex, [Cu(2)(C(14)H(8)O(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(2)], is bisected by a crystallographic twofold axis. Each Cu(II) atom is coordinated in a distorted octahedral geometry by three O atoms from two biphenyl-2,2′-dicarboxylate anions, one aq...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971185/ https://www.ncbi.nlm.nih.gov/pubmed/21578114 http://dx.doi.org/10.1107/S1600536809040628 |
Sumario: | The molecule of the title binuclear copper(II) complex, [Cu(2)(C(14)H(8)O(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(2)], is bisected by a crystallographic twofold axis. Each Cu(II) atom is coordinated in a distorted octahedral geometry by three O atoms from two biphenyl-2,2′-dicarboxylate anions, one aqua O atom and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand. Intramolecular O—H⋯O hydrogen bonds between the coordinated water molecules and the carboxylate O atoms are also present. |
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