Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]

The mol­ecule of the title binuclear copper(II) complex, [Cu(2)(C(14)H(8)O(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(2)], is bis­ected by a crystallographic twofold axis. Each Cu(II) atom is coordinated in a distorted octa­hedral geometry by three O atoms from two biphen­yl-2,2′-dicarboxyl­ate anions, one aq...

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Xi-Yan, Xu, Xiao-Jie, Yang, Lei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971185/
https://www.ncbi.nlm.nih.gov/pubmed/21578114
http://dx.doi.org/10.1107/S1600536809040628
_version_ 1782190566356811776
author Dong, Xi-Yan
Xu, Xiao-Jie
Yang, Lei
author_facet Dong, Xi-Yan
Xu, Xiao-Jie
Yang, Lei
author_sort Dong, Xi-Yan
collection PubMed
description The mol­ecule of the title binuclear copper(II) complex, [Cu(2)(C(14)H(8)O(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(2)], is bis­ected by a crystallographic twofold axis. Each Cu(II) atom is coordinated in a distorted octa­hedral geometry by three O atoms from two biphen­yl-2,2′-dicarboxyl­ate anions, one aqua O atom and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand. Intramolecular O—H⋯O hydrogen bonds between the coordinated water molecules and the carboxylate O atoms are also present.
format Text
id pubmed-2971185
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29711852010-12-30 Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)] Dong, Xi-Yan Xu, Xiao-Jie Yang, Lei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title binuclear copper(II) complex, [Cu(2)(C(14)H(8)O(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(2)], is bis­ected by a crystallographic twofold axis. Each Cu(II) atom is coordinated in a distorted octa­hedral geometry by three O atoms from two biphen­yl-2,2′-dicarboxyl­ate anions, one aqua O atom and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand. Intramolecular O—H⋯O hydrogen bonds between the coordinated water molecules and the carboxylate O atoms are also present. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971185/ /pubmed/21578114 http://dx.doi.org/10.1107/S1600536809040628 Text en © Dong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Xi-Yan
Xu, Xiao-Jie
Yang, Lei
Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]
title Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]
title_full Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]
title_fullStr Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]
title_full_unstemmed Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]
title_short Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]
title_sort bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971185/
https://www.ncbi.nlm.nih.gov/pubmed/21578114
http://dx.doi.org/10.1107/S1600536809040628
work_keys_str_mv AT dongxiyan bismbiphenyl22dicarboxylatobisaqua44dimethyl22bipyridinek2nncopperii
AT xuxiaojie bismbiphenyl22dicarboxylatobisaqua44dimethyl22bipyridinek2nncopperii
AT yanglei bismbiphenyl22dicarboxylatobisaqua44dimethyl22bipyridinek2nncopperii

Ejemplares similares