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(1H-1,3-Benzimidazole-5,6-dicarboxylic acid)(5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid)silver(I) monohydrate

The title compound, [Ag(C(9)H(5)N(2)O(4))(C(9)H(6)N(2)O(4))]·H(2)O, contains one independent Ag atom, a neutral 1H-benzimidazole-5,6-dicarboxylic acid (bdcH), its monodeprotonated form, i.e. 5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid (bdc), and one solvent water mol­ecule, the latter bein...

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Detalles Bibliográficos
Autor principal: Zhai, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971189/
https://www.ncbi.nlm.nih.gov/pubmed/21578205
http://dx.doi.org/10.1107/S1600536809044535
Descripción
Sumario:The title compound, [Ag(C(9)H(5)N(2)O(4))(C(9)H(6)N(2)O(4))]·H(2)O, contains one independent Ag atom, a neutral 1H-benzimidazole-5,6-dicarboxylic acid (bdcH), its monodeprotonated form, i.e. 5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid (bdc), and one solvent water mol­ecule, the latter being disordered over three sites with site occupancy factors of 0.375 (× 2) and 0.25. In addition, the H atom on one carboxylic acid residue is disordered, being connected to each of the O atoms 50% of the time. The Ag atom is in a virtually linear geometry defined by two N atoms derived from the bdc and bdcH ligands. The three-dimensional supra­molecular structure is stablized by extensive O—H⋯O and N—H⋯O hydrogen bonds. An intramolecular O—H⋯O hydrogen bond is also present.