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(1H-1,3-Benzimidazole-5,6-dicarboxylic acid)(5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid)silver(I) monohydrate

The title compound, [Ag(C(9)H(5)N(2)O(4))(C(9)H(6)N(2)O(4))]·H(2)O, contains one independent Ag atom, a neutral 1H-benzimidazole-5,6-dicarboxylic acid (bdcH), its monodeprotonated form, i.e. 5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid (bdc), and one solvent water mol­ecule, the latter bein...

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Autor principal: Zhai, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971189/
https://www.ncbi.nlm.nih.gov/pubmed/21578205
http://dx.doi.org/10.1107/S1600536809044535
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author Zhai, Hong
author_facet Zhai, Hong
author_sort Zhai, Hong
collection PubMed
description The title compound, [Ag(C(9)H(5)N(2)O(4))(C(9)H(6)N(2)O(4))]·H(2)O, contains one independent Ag atom, a neutral 1H-benzimidazole-5,6-dicarboxylic acid (bdcH), its monodeprotonated form, i.e. 5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid (bdc), and one solvent water mol­ecule, the latter being disordered over three sites with site occupancy factors of 0.375 (× 2) and 0.25. In addition, the H atom on one carboxylic acid residue is disordered, being connected to each of the O atoms 50% of the time. The Ag atom is in a virtually linear geometry defined by two N atoms derived from the bdc and bdcH ligands. The three-dimensional supra­molecular structure is stablized by extensive O—H⋯O and N—H⋯O hydrogen bonds. An intramolecular O—H⋯O hydrogen bond is also present.
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spelling pubmed-29711892010-12-30 (1H-1,3-Benzimidazole-5,6-dicarboxylic acid)(5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid)silver(I) monohydrate Zhai, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(C(9)H(5)N(2)O(4))(C(9)H(6)N(2)O(4))]·H(2)O, contains one independent Ag atom, a neutral 1H-benzimidazole-5,6-dicarboxylic acid (bdcH), its monodeprotonated form, i.e. 5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid (bdc), and one solvent water mol­ecule, the latter being disordered over three sites with site occupancy factors of 0.375 (× 2) and 0.25. In addition, the H atom on one carboxylic acid residue is disordered, being connected to each of the O atoms 50% of the time. The Ag atom is in a virtually linear geometry defined by two N atoms derived from the bdc and bdcH ligands. The three-dimensional supra­molecular structure is stablized by extensive O—H⋯O and N—H⋯O hydrogen bonds. An intramolecular O—H⋯O hydrogen bond is also present. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971189/ /pubmed/21578205 http://dx.doi.org/10.1107/S1600536809044535 Text en © Hong Zhai 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhai, Hong
(1H-1,3-Benzimidazole-5,6-dicarboxylic acid)(5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid)silver(I) monohydrate
title (1H-1,3-Benzimidazole-5,6-dicarboxylic acid)(5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid)silver(I) monohydrate
title_full (1H-1,3-Benzimidazole-5,6-dicarboxylic acid)(5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid)silver(I) monohydrate
title_fullStr (1H-1,3-Benzimidazole-5,6-dicarboxylic acid)(5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid)silver(I) monohydrate
title_full_unstemmed (1H-1,3-Benzimidazole-5,6-dicarboxylic acid)(5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid)silver(I) monohydrate
title_short (1H-1,3-Benzimidazole-5,6-dicarboxylic acid)(5-carboxyl­ato-1H-1,3-benzimidazole-6-carboxylic acid)silver(I) monohydrate
title_sort (1h-1,3-benzimidazole-5,6-dicarboxylic acid)(5-carboxyl­ato-1h-1,3-benzimidazole-6-carboxylic acid)silver(i) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971189/
https://www.ncbi.nlm.nih.gov/pubmed/21578205
http://dx.doi.org/10.1107/S1600536809044535
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