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cis-Aquachloridobis(1,10-phenanthroline-κ(2) N,N′)cobalt(II) chloride 2.5-hydrate
In the title complex, [CoCl(C(12)H(8)N(2))(2)(H(2)O)]Cl·2.5H(2)O, the Co(II) ion is coordinated by four N atoms of two bis-chelating 1,10-phenanthroline (phen) ligands, one water molecule and a chloride ligand in a distorted octahedral environment. The dihedral angle between the two phen ligands i...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971197/ https://www.ncbi.nlm.nih.gov/pubmed/21578066 http://dx.doi.org/10.1107/S1600536809038422 |
Sumario: | In the title complex, [CoCl(C(12)H(8)N(2))(2)(H(2)O)]Cl·2.5H(2)O, the Co(II) ion is coordinated by four N atoms of two bis-chelating 1,10-phenanthroline (phen) ligands, one water molecule and a chloride ligand in a distorted octahedral environment. The dihedral angle between the two phen ligands is 84.21 (3)°. In the crystal structure, complex molecules and chloride ions are linked into centrosymmetric four-component clusters by intermolecular O—H⋯Cl hydrogen bonds. Of the 2.5 solvent water molecules in the asymmetric unit, two were refined as disordered over two sites with fixed occupancies of ratios 0.50:0.50 and 0.60:0.40, while another was refined with half occupancy. |
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