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Di-μ(4)-succinato-tetra­kis[aqua­phenanthrolinecopper(II)] tetra­nitrate tetra­hydrate

In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetra­cation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N′-bidentate phenanthroline mol­ecule, two O-monodentate bis-bridging succinate...

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Detalles Bibliográficos
Autores principales: Kitiphaisalnont, Panana, Siripaisarnpipat, Sutatip, Chaichit, Narongsak
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971199/
https://www.ncbi.nlm.nih.gov/pubmed/21578054
http://dx.doi.org/10.1107/S1600536809039580
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author Kitiphaisalnont, Panana
Siripaisarnpipat, Sutatip
Chaichit, Narongsak
author_facet Kitiphaisalnont, Panana
Siripaisarnpipat, Sutatip
Chaichit, Narongsak
author_sort Kitiphaisalnont, Panana
collection PubMed
description In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetra­cation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N′-bidentate phenanthroline mol­ecule, two O-monodentate bis-bridging succinate dianions and a water mol­ecule, resulting in distorted CuN(2)O(3) square-based pyramidal geometries for the metal ions, with the water mol­ecule occupying the apical site. In the crystal, the components are linked by O—H⋯O hydrogen bonds and aromatic π–π stacking inter­actions [minimum centroid–centroid separation = 3.537 (2) Å].
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spelling pubmed-29711992010-12-30 Di-μ(4)-succinato-tetra­kis[aqua­phenanthrolinecopper(II)] tetra­nitrate tetra­hydrate Kitiphaisalnont, Panana Siripaisarnpipat, Sutatip Chaichit, Narongsak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetra­cation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N′-bidentate phenanthroline mol­ecule, two O-monodentate bis-bridging succinate dianions and a water mol­ecule, resulting in distorted CuN(2)O(3) square-based pyramidal geometries for the metal ions, with the water mol­ecule occupying the apical site. In the crystal, the components are linked by O—H⋯O hydrogen bonds and aromatic π–π stacking inter­actions [minimum centroid–centroid separation = 3.537 (2) Å]. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971199/ /pubmed/21578054 http://dx.doi.org/10.1107/S1600536809039580 Text en © Kitiphaisalnont et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kitiphaisalnont, Panana
Siripaisarnpipat, Sutatip
Chaichit, Narongsak
Di-μ(4)-succinato-tetra­kis[aqua­phenanthrolinecopper(II)] tetra­nitrate tetra­hydrate
title Di-μ(4)-succinato-tetra­kis[aqua­phenanthrolinecopper(II)] tetra­nitrate tetra­hydrate
title_full Di-μ(4)-succinato-tetra­kis[aqua­phenanthrolinecopper(II)] tetra­nitrate tetra­hydrate
title_fullStr Di-μ(4)-succinato-tetra­kis[aqua­phenanthrolinecopper(II)] tetra­nitrate tetra­hydrate
title_full_unstemmed Di-μ(4)-succinato-tetra­kis[aqua­phenanthrolinecopper(II)] tetra­nitrate tetra­hydrate
title_short Di-μ(4)-succinato-tetra­kis[aqua­phenanthrolinecopper(II)] tetra­nitrate tetra­hydrate
title_sort di-μ(4)-succinato-tetra­kis[aqua­phenanthrolinecopper(ii)] tetra­nitrate tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971199/
https://www.ncbi.nlm.nih.gov/pubmed/21578054
http://dx.doi.org/10.1107/S1600536809039580
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