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Di-μ(4)-succinato-tetrakis[aquaphenanthrolinecopper(II)] tetranitrate tetrahydrate
In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetracation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N′-bidentate phenanthroline molecule, two O-monodentate bis-bridging succinate...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971199/ https://www.ncbi.nlm.nih.gov/pubmed/21578054 http://dx.doi.org/10.1107/S1600536809039580 |
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author | Kitiphaisalnont, Panana Siripaisarnpipat, Sutatip Chaichit, Narongsak |
author_facet | Kitiphaisalnont, Panana Siripaisarnpipat, Sutatip Chaichit, Narongsak |
author_sort | Kitiphaisalnont, Panana |
collection | PubMed |
description | In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetracation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N′-bidentate phenanthroline molecule, two O-monodentate bis-bridging succinate dianions and a water molecule, resulting in distorted CuN(2)O(3) square-based pyramidal geometries for the metal ions, with the water molecule occupying the apical site. In the crystal, the components are linked by O—H⋯O hydrogen bonds and aromatic π–π stacking interactions [minimum centroid–centroid separation = 3.537 (2) Å]. |
format | Text |
id | pubmed-2971199 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29711992010-12-30 Di-μ(4)-succinato-tetrakis[aquaphenanthrolinecopper(II)] tetranitrate tetrahydrate Kitiphaisalnont, Panana Siripaisarnpipat, Sutatip Chaichit, Narongsak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetracation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N′-bidentate phenanthroline molecule, two O-monodentate bis-bridging succinate dianions and a water molecule, resulting in distorted CuN(2)O(3) square-based pyramidal geometries for the metal ions, with the water molecule occupying the apical site. In the crystal, the components are linked by O—H⋯O hydrogen bonds and aromatic π–π stacking interactions [minimum centroid–centroid separation = 3.537 (2) Å]. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971199/ /pubmed/21578054 http://dx.doi.org/10.1107/S1600536809039580 Text en © Kitiphaisalnont et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kitiphaisalnont, Panana Siripaisarnpipat, Sutatip Chaichit, Narongsak Di-μ(4)-succinato-tetrakis[aquaphenanthrolinecopper(II)] tetranitrate tetrahydrate |
title | Di-μ(4)-succinato-tetrakis[aquaphenanthrolinecopper(II)] tetranitrate tetrahydrate |
title_full | Di-μ(4)-succinato-tetrakis[aquaphenanthrolinecopper(II)] tetranitrate tetrahydrate |
title_fullStr | Di-μ(4)-succinato-tetrakis[aquaphenanthrolinecopper(II)] tetranitrate tetrahydrate |
title_full_unstemmed | Di-μ(4)-succinato-tetrakis[aquaphenanthrolinecopper(II)] tetranitrate tetrahydrate |
title_short | Di-μ(4)-succinato-tetrakis[aquaphenanthrolinecopper(II)] tetranitrate tetrahydrate |
title_sort | di-μ(4)-succinato-tetrakis[aquaphenanthrolinecopper(ii)] tetranitrate tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971199/ https://www.ncbi.nlm.nih.gov/pubmed/21578054 http://dx.doi.org/10.1107/S1600536809039580 |
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