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Dibutyl[N-(5-chloro-2-oxidobenzylidene)-l-isoleucinato-κ(3) O,N,O′]tin(IV)
The Sn(IV) atom of the title compound, [Sn(C(4)H(9))(2)(C(13)H(14)ClNO(3))], adopts a distorted SnNC(2)O(2) trigonal-bipyramidal geometry with a mean Sn—C distance of 2.105 Å and with Sn—O = 2.107 Å, and forms five- and six-membered chelate rings with the tridentate ligand. One butyl group is disord...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971207/ https://www.ncbi.nlm.nih.gov/pubmed/21578068 http://dx.doi.org/10.1107/S1600536809039245 |
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author | Yang, Hong-Jun Dang, Yan-Qiu |
author_facet | Yang, Hong-Jun Dang, Yan-Qiu |
author_sort | Yang, Hong-Jun |
collection | PubMed |
description | The Sn(IV) atom of the title compound, [Sn(C(4)H(9))(2)(C(13)H(14)ClNO(3))], adopts a distorted SnNC(2)O(2) trigonal-bipyramidal geometry with a mean Sn—C distance of 2.105 Å and with Sn—O = 2.107 Å, and forms five- and six-membered chelate rings with the tridentate ligand. One butyl group is disordered over two positions with site occupancies of 0.65 (1):0.35 (1). |
format | Text |
id | pubmed-2971207 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29712072010-12-30 Dibutyl[N-(5-chloro-2-oxidobenzylidene)-l-isoleucinato-κ(3) O,N,O′]tin(IV) Yang, Hong-Jun Dang, Yan-Qiu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom of the title compound, [Sn(C(4)H(9))(2)(C(13)H(14)ClNO(3))], adopts a distorted SnNC(2)O(2) trigonal-bipyramidal geometry with a mean Sn—C distance of 2.105 Å and with Sn—O = 2.107 Å, and forms five- and six-membered chelate rings with the tridentate ligand. One butyl group is disordered over two positions with site occupancies of 0.65 (1):0.35 (1). International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971207/ /pubmed/21578068 http://dx.doi.org/10.1107/S1600536809039245 Text en © Yang and Dang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Hong-Jun Dang, Yan-Qiu Dibutyl[N-(5-chloro-2-oxidobenzylidene)-l-isoleucinato-κ(3) O,N,O′]tin(IV) |
title | Dibutyl[N-(5-chloro-2-oxidobenzylidene)-l-isoleucinato-κ(3)
O,N,O′]tin(IV) |
title_full | Dibutyl[N-(5-chloro-2-oxidobenzylidene)-l-isoleucinato-κ(3)
O,N,O′]tin(IV) |
title_fullStr | Dibutyl[N-(5-chloro-2-oxidobenzylidene)-l-isoleucinato-κ(3)
O,N,O′]tin(IV) |
title_full_unstemmed | Dibutyl[N-(5-chloro-2-oxidobenzylidene)-l-isoleucinato-κ(3)
O,N,O′]tin(IV) |
title_short | Dibutyl[N-(5-chloro-2-oxidobenzylidene)-l-isoleucinato-κ(3)
O,N,O′]tin(IV) |
title_sort | dibutyl[n-(5-chloro-2-oxidobenzylidene)-l-isoleucinato-κ(3)
o,n,o′]tin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971207/ https://www.ncbi.nlm.nih.gov/pubmed/21578068 http://dx.doi.org/10.1107/S1600536809039245 |
work_keys_str_mv | AT yanghongjun dibutyln5chloro2oxidobenzylidenelisoleucinatok3onotiniv AT dangyanqiu dibutyln5chloro2oxidobenzylidenelisoleucinatok3onotiniv |