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Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(II)

There are two half-mol­ecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear mol­ecule. In both mol­ecules, the central Cu atom (site symmetry [Image: see text]) adopts a distorted trans-CuO...

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Detalles Bibliográficos
Autores principales: Gao, Jin-Ping, Zhang, Wen, Shi, Xue-Feng, Li, Da-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971209/
https://www.ncbi.nlm.nih.gov/pubmed/21578183
http://dx.doi.org/10.1107/S160053680904389X
Descripción
Sumario:There are two half-mol­ecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear mol­ecule. In both mol­ecules, the central Cu atom (site symmetry [Image: see text]) adopts a distorted trans-CuO(2)N(4) octa­hedral geometry, arising from its coordination by two N,O-bidentate aroylhydrazine ligands and two pyridine mol­ecules. The peripheral Cu atoms adopt trans-CuN(2)O(2) square-planar coordinations arising from an N,O,O-tri­dentate ligand (that also bonds to the central Cu atom) and a pyridine mol­ecule.