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Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II)
There are two half-molecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear molecule. In both molecules, the central Cu atom (site symmetry [Image: see text]) adopts a distorted trans-CuO...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971209/ https://www.ncbi.nlm.nih.gov/pubmed/21578183 http://dx.doi.org/10.1107/S160053680904389X |
Sumario: | There are two half-molecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear molecule. In both molecules, the central Cu atom (site symmetry [Image: see text]) adopts a distorted trans-CuO(2)N(4) octahedral geometry, arising from its coordination by two N,O-bidentate aroylhydrazine ligands and two pyridine molecules. The peripheral Cu atoms adopt trans-CuN(2)O(2) square-planar coordinations arising from an N,O,O-tridentate ligand (that also bonds to the central Cu atom) and a pyridine molecule. |
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