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Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II)
There are two half-molecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear molecule. In both molecules, the central Cu atom (site symmetry [Image: see text]) adopts a distorted trans-CuO...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971209/ https://www.ncbi.nlm.nih.gov/pubmed/21578183 http://dx.doi.org/10.1107/S160053680904389X |
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author | Gao, Jin-Ping Zhang, Wen Shi, Xue-Feng Li, Da-Cheng |
author_facet | Gao, Jin-Ping Zhang, Wen Shi, Xue-Feng Li, Da-Cheng |
author_sort | Gao, Jin-Ping |
collection | PubMed |
description | There are two half-molecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear molecule. In both molecules, the central Cu atom (site symmetry [Image: see text]) adopts a distorted trans-CuO(2)N(4) octahedral geometry, arising from its coordination by two N,O-bidentate aroylhydrazine ligands and two pyridine molecules. The peripheral Cu atoms adopt trans-CuN(2)O(2) square-planar coordinations arising from an N,O,O-tridentate ligand (that also bonds to the central Cu atom) and a pyridine molecule. |
format | Text |
id | pubmed-2971209 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29712092010-12-30 Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) Gao, Jin-Ping Zhang, Wen Shi, Xue-Feng Li, Da-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are two half-molecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear molecule. In both molecules, the central Cu atom (site symmetry [Image: see text]) adopts a distorted trans-CuO(2)N(4) octahedral geometry, arising from its coordination by two N,O-bidentate aroylhydrazine ligands and two pyridine molecules. The peripheral Cu atoms adopt trans-CuN(2)O(2) square-planar coordinations arising from an N,O,O-tridentate ligand (that also bonds to the central Cu atom) and a pyridine molecule. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971209/ /pubmed/21578183 http://dx.doi.org/10.1107/S160053680904389X Text en © Gao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Jin-Ping Zhang, Wen Shi, Xue-Feng Li, Da-Cheng Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
title | Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
title_full | Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
title_fullStr | Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
title_full_unstemmed | Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
title_short | Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
title_sort | bis[μ-n′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971209/ https://www.ncbi.nlm.nih.gov/pubmed/21578183 http://dx.doi.org/10.1107/S160053680904389X |
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