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Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(II)

There are two half-mol­ecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear mol­ecule. In both mol­ecules, the central Cu atom (site symmetry [Image: see text]) adopts a distorted trans-CuO...

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Detalles Bibliográficos
Autores principales: Gao, Jin-Ping, Zhang, Wen, Shi, Xue-Feng, Li, Da-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971209/
https://www.ncbi.nlm.nih.gov/pubmed/21578183
http://dx.doi.org/10.1107/S160053680904389X
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author Gao, Jin-Ping
Zhang, Wen
Shi, Xue-Feng
Li, Da-Cheng
author_facet Gao, Jin-Ping
Zhang, Wen
Shi, Xue-Feng
Li, Da-Cheng
author_sort Gao, Jin-Ping
collection PubMed
description There are two half-mol­ecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear mol­ecule. In both mol­ecules, the central Cu atom (site symmetry [Image: see text]) adopts a distorted trans-CuO(2)N(4) octa­hedral geometry, arising from its coordination by two N,O-bidentate aroylhydrazine ligands and two pyridine mol­ecules. The peripheral Cu atoms adopt trans-CuN(2)O(2) square-planar coordinations arising from an N,O,O-tri­dentate ligand (that also bonds to the central Cu atom) and a pyridine mol­ecule.
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spelling pubmed-29712092010-12-30 Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(II) Gao, Jin-Ping Zhang, Wen Shi, Xue-Feng Li, Da-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are two half-mol­ecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear mol­ecule. In both mol­ecules, the central Cu atom (site symmetry [Image: see text]) adopts a distorted trans-CuO(2)N(4) octa­hedral geometry, arising from its coordination by two N,O-bidentate aroylhydrazine ligands and two pyridine mol­ecules. The peripheral Cu atoms adopt trans-CuN(2)O(2) square-planar coordinations arising from an N,O,O-tri­dentate ligand (that also bonds to the central Cu atom) and a pyridine mol­ecule. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971209/ /pubmed/21578183 http://dx.doi.org/10.1107/S160053680904389X Text en © Gao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Jin-Ping
Zhang, Wen
Shi, Xue-Feng
Li, Da-Cheng
Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(II)
title Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(II)
title_full Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(II)
title_fullStr Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(II)
title_full_unstemmed Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(II)
title_short Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(II)
title_sort bis[μ-n′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971209/
https://www.ncbi.nlm.nih.gov/pubmed/21578183
http://dx.doi.org/10.1107/S160053680904389X
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