(μ-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]

The dinuclear title compound, [Zn(2)(C(3)H(6)NS(2))(4)(C(12)H(10)N(2))], features two five-coordinate Zn atoms, one with an NS(4) coordination geometry distorted towards a trigonal-bipyramidal arrangement, and the other distorted towards a square pyramid. In the crystal, mol­ecules are connected int...

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Detalles Bibliográficos
Autores principales: Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971210/
https://www.ncbi.nlm.nih.gov/pubmed/21578197
http://dx.doi.org/10.1107/S1600536809044249
Descripción
Sumario:The dinuclear title compound, [Zn(2)(C(3)H(6)NS(2))(4)(C(12)H(10)N(2))], features two five-coordinate Zn atoms, one with an NS(4) coordination geometry distorted towards a trigonal-bipyramidal arrangement, and the other distorted towards a square pyramid. In the crystal, mol­ecules are connected into supra­molecular zigzag chains via C—H⋯S contacts. Chains are connected via C—H⋯π interactions, consolidating the crystal packing.

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