(μ-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]

The dinuclear title compound, [Zn(2)(C(3)H(6)NS(2))(4)(C(12)H(10)N(2))], features two five-coordinate Zn atoms, one with an NS(4) coordination geometry distorted towards a trigonal-bipyramidal arrangement, and the other distorted towards a square pyramid. In the crystal, mol­ecules are connected int...

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Detalles Bibliográficos
Autores principales: Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971210/
https://www.ncbi.nlm.nih.gov/pubmed/21578197
http://dx.doi.org/10.1107/S1600536809044249
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author Poplaukhin, Pavel
Tiekink, Edward R. T.
author_facet Poplaukhin, Pavel
Tiekink, Edward R. T.
author_sort Poplaukhin, Pavel
collection PubMed
description The dinuclear title compound, [Zn(2)(C(3)H(6)NS(2))(4)(C(12)H(10)N(2))], features two five-coordinate Zn atoms, one with an NS(4) coordination geometry distorted towards a trigonal-bipyramidal arrangement, and the other distorted towards a square pyramid. In the crystal, mol­ecules are connected into supra­molecular zigzag chains via C—H⋯S contacts. Chains are connected via C—H⋯π interactions, consolidating the crystal packing.
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spelling pubmed-29712102010-12-30 (μ-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Zn(2)(C(3)H(6)NS(2))(4)(C(12)H(10)N(2))], features two five-coordinate Zn atoms, one with an NS(4) coordination geometry distorted towards a trigonal-bipyramidal arrangement, and the other distorted towards a square pyramid. In the crystal, mol­ecules are connected into supra­molecular zigzag chains via C—H⋯S contacts. Chains are connected via C—H⋯π interactions, consolidating the crystal packing. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971210/ /pubmed/21578197 http://dx.doi.org/10.1107/S1600536809044249 Text en © Poplaukhin and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Poplaukhin, Pavel
Tiekink, Edward R. T.
(μ-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title (μ-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_full (μ-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_fullStr (μ-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_full_unstemmed (μ-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_short (μ-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_sort (μ-1,2-di-4-pyridylethyl­ene-κ(2) n:n′)bis­[bis­(n,n-dimethyl­dithio­carbamato-κ(2) s,s′)zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971210/
https://www.ncbi.nlm.nih.gov/pubmed/21578197
http://dx.doi.org/10.1107/S1600536809044249
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AT tiekinkedwardrt m12di4pyridylethylenek2nnbisbisnndimethyldithiocarbamatok2sszincii

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