2-Hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxylic acid

The title compound, C(10)H(16)O(3), with a bicyclo­[3.1.1]heptane unit, was obtained by oxidation of β-pinene. The asymmetric unit contains two independent mol­ecules with similar geometry: the six-membered rings in both mol­ecules adopt envelope conformations. In the crystal, the independent mol­ec...

Descripción completa

Detalles Bibliográficos
Autores principales: Gao, Yan-Qing, Shang, Shi-Bin, Xu, Xu, Rao, Xiao-Ping, Wang, Hong-Xiao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971213/
https://www.ncbi.nlm.nih.gov/pubmed/21578342
http://dx.doi.org/10.1107/S1600536809041385
_version_ 1782190573189332992
author Gao, Yan-Qing
Shang, Shi-Bin
Xu, Xu
Rao, Xiao-Ping
Wang, Hong-Xiao
author_facet Gao, Yan-Qing
Shang, Shi-Bin
Xu, Xu
Rao, Xiao-Ping
Wang, Hong-Xiao
author_sort Gao, Yan-Qing
collection PubMed
description The title compound, C(10)H(16)O(3), with a bicyclo­[3.1.1]heptane unit, was obtained by oxidation of β-pinene. The asymmetric unit contains two independent mol­ecules with similar geometry: the six-membered rings in both mol­ecules adopt envelope conformations. In the crystal, the independent mol­ecules exist as O—H⋯O hydrogen-bonded dimers. The dimers are linked into helical chains along the b axis by O—H⋯O hydrogen bonds.
format Text
id pubmed-2971213
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29712132010-12-30 2-Hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxylic acid Gao, Yan-Qing Shang, Shi-Bin Xu, Xu Rao, Xiao-Ping Wang, Hong-Xiao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(16)O(3), with a bicyclo­[3.1.1]heptane unit, was obtained by oxidation of β-pinene. The asymmetric unit contains two independent mol­ecules with similar geometry: the six-membered rings in both mol­ecules adopt envelope conformations. In the crystal, the independent mol­ecules exist as O—H⋯O hydrogen-bonded dimers. The dimers are linked into helical chains along the b axis by O—H⋯O hydrogen bonds. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971213/ /pubmed/21578342 http://dx.doi.org/10.1107/S1600536809041385 Text en © Gao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gao, Yan-Qing
Shang, Shi-Bin
Xu, Xu
Rao, Xiao-Ping
Wang, Hong-Xiao
2-Hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxylic acid
title 2-Hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxylic acid
title_full 2-Hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxylic acid
title_fullStr 2-Hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxylic acid
title_full_unstemmed 2-Hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxylic acid
title_short 2-Hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxylic acid
title_sort 2-hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxylic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971213/
https://www.ncbi.nlm.nih.gov/pubmed/21578342
http://dx.doi.org/10.1107/S1600536809041385
work_keys_str_mv AT gaoyanqing 2hydroxy66dimethylbicyclo311heptane2carboxylicacid
AT shangshibin 2hydroxy66dimethylbicyclo311heptane2carboxylicacid
AT xuxu 2hydroxy66dimethylbicyclo311heptane2carboxylicacid
AT raoxiaoping 2hydroxy66dimethylbicyclo311heptane2carboxylicacid
AT wanghongxiao 2hydroxy66dimethylbicyclo311heptane2carboxylicacid

Ejemplares similares