(μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]

The dinuclear title compound, [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(2))], is centrosymmetric about the central C=C bond. The five-coordinate Zn atom is bonded to two asymmetrically chelating dithio­carbamate ligands and a pyridine N atom to define an NS(4) coordination geometry tending towards a squ...

Descripción completa

Detalles Bibliográficos
Autores principales: Arman, Hadi D., Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971214/
https://www.ncbi.nlm.nih.gov/pubmed/21578198
http://dx.doi.org/10.1107/S1600536809044250
_version_ 1782190573428408320
author Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The dinuclear title compound, [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(2))], is centrosymmetric about the central C=C bond. The five-coordinate Zn atom is bonded to two asymmetrically chelating dithio­carbamate ligands and a pyridine N atom to define an NS(4) coordination geometry tending towards a square pyramid, with the N atom in the apical site. In the crystal structure, C—H⋯S contacts lead to supra­molecular chains.
format Text
id pubmed-2971214
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29712142010-12-30 (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)] Arman, Hadi D. Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(2))], is centrosymmetric about the central C=C bond. The five-coordinate Zn atom is bonded to two asymmetrically chelating dithio­carbamate ligands and a pyridine N atom to define an NS(4) coordination geometry tending towards a square pyramid, with the N atom in the apical site. In the crystal structure, C—H⋯S contacts lead to supra­molecular chains. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971214/ /pubmed/21578198 http://dx.doi.org/10.1107/S1600536809044250 Text en © Arman et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
(μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_full (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_fullStr (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_full_unstemmed (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_short (μ-trans-1,2-Di-4-pyridylethyl­ene-κ(2) N:N′)bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_sort (μ-trans-1,2-di-4-pyridylethyl­ene-κ(2) n:n′)bis­[bis­(n,n-diisopropyl­dithio­carbamato-κ(2) s,s′)zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971214/
https://www.ncbi.nlm.nih.gov/pubmed/21578198
http://dx.doi.org/10.1107/S1600536809044250
work_keys_str_mv AT armanhadid mtrans12di4pyridylethylenek2nnbisbisnndiisopropyldithiocarbamatok2sszincii
AT poplaukhinpavel mtrans12di4pyridylethylenek2nnbisbisnndiisopropyldithiocarbamatok2sszincii
AT tiekinkedwardrt mtrans12di4pyridylethylenek2nnbisbisnndiisopropyldithiocarbamatok2sszincii

Ejemplares similares