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(E)-1-Methyl-4-styrylpyridinium iodide monohydrate

In the title compound, C(14)H(14)N(+)·I(−)·H(2)O, the cation is essentially planar, with a dihedral angle of 2.55 (7)° between the pyridinium and phenyl rings, and exists in an E configuration with respect to the ethenyl bond. In the crystal structure, the cations are stacked in an anti­parallel man...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Surasit, Chanasuk, Chanawanno, Kullapa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971221/
https://www.ncbi.nlm.nih.gov/pubmed/21578284
http://dx.doi.org/10.1107/S1600536809040446
Descripción
Sumario:In the title compound, C(14)H(14)N(+)·I(−)·H(2)O, the cation is essentially planar, with a dihedral angle of 2.55 (7)° between the pyridinium and phenyl rings, and exists in an E configuration with respect to the ethenyl bond. In the crystal structure, the cations are stacked in an anti­parallel manner along the a axis. The cation is linked to the water mol­ecule by a weak C—H⋯O inter­action, and the water mol­ecule is further linked to the I(−) ion by O—H⋯I hydrogen bonds. The crystal structure is consolidated by these inter­actions and is further stabilized by a π–π inter­action between the pyridinium and phenyl rings with a centroid–centroid distance of 3.6850 (8) Å.