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(E)-1-Methyl-4-styrylpyridinium iodide monohydrate

In the title compound, C(14)H(14)N(+)·I(−)·H(2)O, the cation is essentially planar, with a dihedral angle of 2.55 (7)° between the pyridinium and phenyl rings, and exists in an E configuration with respect to the ethenyl bond. In the crystal structure, the cations are stacked in an anti­parallel man...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Surasit, Chanasuk, Chanawanno, Kullapa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971221/
https://www.ncbi.nlm.nih.gov/pubmed/21578284
http://dx.doi.org/10.1107/S1600536809040446
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author Fun, Hoong-Kun
Chantrapromma, Suchada
Surasit, Chanasuk
Chanawanno, Kullapa
author_facet Fun, Hoong-Kun
Chantrapromma, Suchada
Surasit, Chanasuk
Chanawanno, Kullapa
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(14)H(14)N(+)·I(−)·H(2)O, the cation is essentially planar, with a dihedral angle of 2.55 (7)° between the pyridinium and phenyl rings, and exists in an E configuration with respect to the ethenyl bond. In the crystal structure, the cations are stacked in an anti­parallel manner along the a axis. The cation is linked to the water mol­ecule by a weak C—H⋯O inter­action, and the water mol­ecule is further linked to the I(−) ion by O—H⋯I hydrogen bonds. The crystal structure is consolidated by these inter­actions and is further stabilized by a π–π inter­action between the pyridinium and phenyl rings with a centroid–centroid distance of 3.6850 (8) Å.
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spelling pubmed-29712212010-12-30 (E)-1-Methyl-4-styrylpyridinium iodide monohydrate Fun, Hoong-Kun Chantrapromma, Suchada Surasit, Chanasuk Chanawanno, Kullapa Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)N(+)·I(−)·H(2)O, the cation is essentially planar, with a dihedral angle of 2.55 (7)° between the pyridinium and phenyl rings, and exists in an E configuration with respect to the ethenyl bond. In the crystal structure, the cations are stacked in an anti­parallel manner along the a axis. The cation is linked to the water mol­ecule by a weak C—H⋯O inter­action, and the water mol­ecule is further linked to the I(−) ion by O—H⋯I hydrogen bonds. The crystal structure is consolidated by these inter­actions and is further stabilized by a π–π inter­action between the pyridinium and phenyl rings with a centroid–centroid distance of 3.6850 (8) Å. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971221/ /pubmed/21578284 http://dx.doi.org/10.1107/S1600536809040446 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chantrapromma, Suchada
Surasit, Chanasuk
Chanawanno, Kullapa
(E)-1-Methyl-4-styrylpyridinium iodide monohydrate
title (E)-1-Methyl-4-styrylpyridinium iodide monohydrate
title_full (E)-1-Methyl-4-styrylpyridinium iodide monohydrate
title_fullStr (E)-1-Methyl-4-styrylpyridinium iodide monohydrate
title_full_unstemmed (E)-1-Methyl-4-styrylpyridinium iodide monohydrate
title_short (E)-1-Methyl-4-styrylpyridinium iodide monohydrate
title_sort (e)-1-methyl-4-styrylpyridinium iodide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971221/
https://www.ncbi.nlm.nih.gov/pubmed/21578284
http://dx.doi.org/10.1107/S1600536809040446
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