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Tetraethylammonium hexacyanidoferrate(III) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2)
In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971224/ https://www.ncbi.nlm.nih.gov/pubmed/21578133 http://dx.doi.org/10.1107/S1600536809037490 |
Sumario: | In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen)(H(2)O)(2)](+) coordination cation, one half of a C (2) symmetric [Fe(CN)(6)](3−) anion and disordered methanol and ethanol solvent molecules that are equally populated at two different sites. The Mn(III) atom chelated by the 3-Meosalophen ligand adopts a slightly distorted MnN(2)O(4) octahedral geometry with the coordination completed by two water molecules. The [Mn(3-Meosalophen)(H(2)O)(2)](+) cations, [Fe(CN)(6)](3- )anions and solvent molecules are connected into a zigzag chain through hydrogen-bonding interactions. |
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