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Tetraethylammonium hexacyanidoferrate(III) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2)
In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971224/ https://www.ncbi.nlm.nih.gov/pubmed/21578133 http://dx.doi.org/10.1107/S1600536809037490 |
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author | Wang, Ting-Ting Xie, Ji-Min |
author_facet | Wang, Ting-Ting Xie, Ji-Min |
author_sort | Wang, Ting-Ting |
collection | PubMed |
description | In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen)(H(2)O)(2)](+) coordination cation, one half of a C (2) symmetric [Fe(CN)(6)](3−) anion and disordered methanol and ethanol solvent molecules that are equally populated at two different sites. The Mn(III) atom chelated by the 3-Meosalophen ligand adopts a slightly distorted MnN(2)O(4) octahedral geometry with the coordination completed by two water molecules. The [Mn(3-Meosalophen)(H(2)O)(2)](+) cations, [Fe(CN)(6)](3- )anions and solvent molecules are connected into a zigzag chain through hydrogen-bonding interactions. |
format | Text |
id | pubmed-2971224 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29712242010-12-30 Tetraethylammonium hexacyanidoferrate(III) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2) Wang, Ting-Ting Xie, Ji-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen)(H(2)O)(2)](+) coordination cation, one half of a C (2) symmetric [Fe(CN)(6)](3−) anion and disordered methanol and ethanol solvent molecules that are equally populated at two different sites. The Mn(III) atom chelated by the 3-Meosalophen ligand adopts a slightly distorted MnN(2)O(4) octahedral geometry with the coordination completed by two water molecules. The [Mn(3-Meosalophen)(H(2)O)(2)](+) cations, [Fe(CN)(6)](3- )anions and solvent molecules are connected into a zigzag chain through hydrogen-bonding interactions. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971224/ /pubmed/21578133 http://dx.doi.org/10.1107/S1600536809037490 Text en © Wang and Xie 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Ting-Ting Xie, Ji-Min Tetraethylammonium hexacyanidoferrate(III) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2) |
title | Tetraethylammonium hexacyanidoferrate(III) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2) |
title_full | Tetraethylammonium hexacyanidoferrate(III) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2) |
title_fullStr | Tetraethylammonium hexacyanidoferrate(III) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2) |
title_full_unstemmed | Tetraethylammonium hexacyanidoferrate(III) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2) |
title_short | Tetraethylammonium hexacyanidoferrate(III) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2) |
title_sort | tetraethylammonium hexacyanidoferrate(iii) bis(diaqua{6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}manganese(iii))–methanol–ethanol (1/2/2) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971224/ https://www.ncbi.nlm.nih.gov/pubmed/21578133 http://dx.doi.org/10.1107/S1600536809037490 |
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