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Tetra­ethyl­ammonium hexa­cyanidoferrate(III) bis­(diaqua­{6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2)

In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen...

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Detalles Bibliográficos
Autores principales: Wang, Ting-Ting, Xie, Ji-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971224/
https://www.ncbi.nlm.nih.gov/pubmed/21578133
http://dx.doi.org/10.1107/S1600536809037490
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author Wang, Ting-Ting
Xie, Ji-Min
author_facet Wang, Ting-Ting
Xie, Ji-Min
author_sort Wang, Ting-Ting
collection PubMed
description In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen)(H(2)O)(2)](+) coordination cation, one half of a C (2) symmetric [Fe(CN)(6)](3−) anion and disordered methanol and ethanol solvent mol­ecules that are equally populated at two different sites. The Mn(III) atom chelated by the 3-Meosalophen ligand adopts a slightly distorted MnN(2)O(4) octa­hedral geometry with the coordination completed by two water mol­ecules. The [Mn(3-Meosalophen)(H(2)O)(2)](+) cations, [Fe(CN)(6)](3- )anions and solvent mol­ecules are connected into a zigzag chain through hydrogen-bonding inter­actions.
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spelling pubmed-29712242010-12-30 Tetra­ethyl­ammonium hexa­cyanidoferrate(III) bis­(diaqua­{6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2) Wang, Ting-Ting Xie, Ji-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen)(H(2)O)(2)](+) coordination cation, one half of a C (2) symmetric [Fe(CN)(6)](3−) anion and disordered methanol and ethanol solvent mol­ecules that are equally populated at two different sites. The Mn(III) atom chelated by the 3-Meosalophen ligand adopts a slightly distorted MnN(2)O(4) octa­hedral geometry with the coordination completed by two water mol­ecules. The [Mn(3-Meosalophen)(H(2)O)(2)](+) cations, [Fe(CN)(6)](3- )anions and solvent mol­ecules are connected into a zigzag chain through hydrogen-bonding inter­actions. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971224/ /pubmed/21578133 http://dx.doi.org/10.1107/S1600536809037490 Text en © Wang and Xie 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ting-Ting
Xie, Ji-Min
Tetra­ethyl­ammonium hexa­cyanidoferrate(III) bis­(diaqua­{6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2)
title Tetra­ethyl­ammonium hexa­cyanidoferrate(III) bis­(diaqua­{6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2)
title_full Tetra­ethyl­ammonium hexa­cyanidoferrate(III) bis­(diaqua­{6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2)
title_fullStr Tetra­ethyl­ammonium hexa­cyanidoferrate(III) bis­(diaqua­{6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2)
title_full_unstemmed Tetra­ethyl­ammonium hexa­cyanidoferrate(III) bis­(diaqua­{6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2)
title_short Tetra­ethyl­ammonium hexa­cyanidoferrate(III) bis­(diaqua­{6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}manganese(III))–methanol–ethanol (1/2/2)
title_sort tetra­ethyl­ammonium hexa­cyanidoferrate(iii) bis­(diaqua­{6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}manganese(iii))–methanol–ethanol (1/2/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971224/
https://www.ncbi.nlm.nih.gov/pubmed/21578133
http://dx.doi.org/10.1107/S1600536809037490
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AT xiejimin tetraethylammoniumhexacyanidoferrateiiibisdiaqua66dimethoxy22ophenylenebisnitrilomethylidynediphenolatomanganeseiiimethanolethanol122