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5-Methyl-3-[1-(2-pyridylmeth­yl)-1H-benzimidazol-2-ylmeth­yl]isoxazole

The title compound, C(18)H(16)N(4)O, is built up from fused six- and five-membered rings linked to a five-membered isoxazole ring and to a six-membered pyridine ring through a CH(2) group. The fused-ring system is essentially planar, with a maximum deviation of 0.019 (1) Å. It forms inter­planar ang...

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Autores principales: Doumbia, Mohamadou Lamine, Bouhfid, Rachid, Essassi, El Mokhtar, El Ammari, Lahcen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971225/
https://www.ncbi.nlm.nih.gov/pubmed/21578313
http://dx.doi.org/10.1107/S1600536809040100
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author Doumbia, Mohamadou Lamine
Bouhfid, Rachid
Essassi, El Mokhtar
El Ammari, Lahcen
author_facet Doumbia, Mohamadou Lamine
Bouhfid, Rachid
Essassi, El Mokhtar
El Ammari, Lahcen
author_sort Doumbia, Mohamadou Lamine
collection PubMed
description The title compound, C(18)H(16)N(4)O, is built up from fused six- and five-membered rings linked to a five-membered isoxazole ring and to a six-membered pyridine ring through a CH(2) group. The fused-ring system is essentially planar, with a maximum deviation of 0.019 (1) Å. It forms inter­planar angles of 70.03 (7)° with the isoxazole ring and 81.68 (7)° with the pyridine ring; the two latter rings are also planar, the maximum deviations from the mean planes being 0.0028 (15) and 0.0047 (12) Å, respectively. In the crystal, weak inter­molecular non-classical C—H⋯N hydrogen bonds link the mol­ecules, forming a zigzag-like chain parallel to the b axis. A weak intra­molecular C—H⋯N hydrogen bond may help to define the conformation of the mol­ecule.
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spelling pubmed-29712252010-12-30 5-Methyl-3-[1-(2-pyridylmeth­yl)-1H-benzimidazol-2-ylmeth­yl]isoxazole Doumbia, Mohamadou Lamine Bouhfid, Rachid Essassi, El Mokhtar El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(16)N(4)O, is built up from fused six- and five-membered rings linked to a five-membered isoxazole ring and to a six-membered pyridine ring through a CH(2) group. The fused-ring system is essentially planar, with a maximum deviation of 0.019 (1) Å. It forms inter­planar angles of 70.03 (7)° with the isoxazole ring and 81.68 (7)° with the pyridine ring; the two latter rings are also planar, the maximum deviations from the mean planes being 0.0028 (15) and 0.0047 (12) Å, respectively. In the crystal, weak inter­molecular non-classical C—H⋯N hydrogen bonds link the mol­ecules, forming a zigzag-like chain parallel to the b axis. A weak intra­molecular C—H⋯N hydrogen bond may help to define the conformation of the mol­ecule. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971225/ /pubmed/21578313 http://dx.doi.org/10.1107/S1600536809040100 Text en © Doumbia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Doumbia, Mohamadou Lamine
Bouhfid, Rachid
Essassi, El Mokhtar
El Ammari, Lahcen
5-Methyl-3-[1-(2-pyridylmeth­yl)-1H-benzimidazol-2-ylmeth­yl]isoxazole
title 5-Methyl-3-[1-(2-pyridylmeth­yl)-1H-benzimidazol-2-ylmeth­yl]isoxazole
title_full 5-Methyl-3-[1-(2-pyridylmeth­yl)-1H-benzimidazol-2-ylmeth­yl]isoxazole
title_fullStr 5-Methyl-3-[1-(2-pyridylmeth­yl)-1H-benzimidazol-2-ylmeth­yl]isoxazole
title_full_unstemmed 5-Methyl-3-[1-(2-pyridylmeth­yl)-1H-benzimidazol-2-ylmeth­yl]isoxazole
title_short 5-Methyl-3-[1-(2-pyridylmeth­yl)-1H-benzimidazol-2-ylmeth­yl]isoxazole
title_sort 5-methyl-3-[1-(2-pyridylmeth­yl)-1h-benzimidazol-2-ylmeth­yl]isoxazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971225/
https://www.ncbi.nlm.nih.gov/pubmed/21578313
http://dx.doi.org/10.1107/S1600536809040100
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