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Methano­ldinitrato[N-(2-pyridylmethyl­ene)aniline]copper(II)

The Cu atom in the title compound, [Cu(NO(3))(2)(C(12)H(10)N(2))(CH(3)OH)], adopts a square-pyramidal geometry, being ligated by two N atoms of the bidentate N-(2-pyridylmethyl­ene)­aniline (ppma) ligand, two O atoms of NO(3) ligands and one O atom of a methanol molecule, which occupies the apical p...

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Detalles Bibliográficos
Autores principales: Kim, Young-Inn, Lee, Hong Woo, Kim, Ji-Hoon, Park, Sun Young, Kang, Sung Kwon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971227/
https://www.ncbi.nlm.nih.gov/pubmed/21578116
http://dx.doi.org/10.1107/S1600536809041075
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author Kim, Young-Inn
Lee, Hong Woo
Kim, Ji-Hoon
Park, Sun Young
Kang, Sung Kwon
author_facet Kim, Young-Inn
Lee, Hong Woo
Kim, Ji-Hoon
Park, Sun Young
Kang, Sung Kwon
author_sort Kim, Young-Inn
collection PubMed
description The Cu atom in the title compound, [Cu(NO(3))(2)(C(12)H(10)N(2))(CH(3)OH)], adopts a square-pyramidal geometry, being ligated by two N atoms of the bidentate N-(2-pyridylmethyl­ene)­aniline (ppma) ligand, two O atoms of NO(3) ligands and one O atom of a methanol molecule, which occupies the apical position. The phenyl ring on the ppma ligand is twisted out of the pyridine plane, forming a dihedral angle of 42.9 (1)°. In the crystal, inter­molecular O—H⋯O hydrogen bonds between methanol and NO(3) ligands form an extensive one-dimensional network extending parallel to [100].
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spelling pubmed-29712272010-12-30 Methano­ldinitrato[N-(2-pyridylmethyl­ene)aniline]copper(II) Kim, Young-Inn Lee, Hong Woo Kim, Ji-Hoon Park, Sun Young Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu atom in the title compound, [Cu(NO(3))(2)(C(12)H(10)N(2))(CH(3)OH)], adopts a square-pyramidal geometry, being ligated by two N atoms of the bidentate N-(2-pyridylmethyl­ene)­aniline (ppma) ligand, two O atoms of NO(3) ligands and one O atom of a methanol molecule, which occupies the apical position. The phenyl ring on the ppma ligand is twisted out of the pyridine plane, forming a dihedral angle of 42.9 (1)°. In the crystal, inter­molecular O—H⋯O hydrogen bonds between methanol and NO(3) ligands form an extensive one-dimensional network extending parallel to [100]. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971227/ /pubmed/21578116 http://dx.doi.org/10.1107/S1600536809041075 Text en © Kim et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Young-Inn
Lee, Hong Woo
Kim, Ji-Hoon
Park, Sun Young
Kang, Sung Kwon
Methano­ldinitrato[N-(2-pyridylmethyl­ene)aniline]copper(II)
title Methano­ldinitrato[N-(2-pyridylmethyl­ene)aniline]copper(II)
title_full Methano­ldinitrato[N-(2-pyridylmethyl­ene)aniline]copper(II)
title_fullStr Methano­ldinitrato[N-(2-pyridylmethyl­ene)aniline]copper(II)
title_full_unstemmed Methano­ldinitrato[N-(2-pyridylmethyl­ene)aniline]copper(II)
title_short Methano­ldinitrato[N-(2-pyridylmethyl­ene)aniline]copper(II)
title_sort methano­ldinitrato[n-(2-pyridylmethyl­ene)aniline]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971227/
https://www.ncbi.nlm.nih.gov/pubmed/21578116
http://dx.doi.org/10.1107/S1600536809041075
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