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Methanoldinitrato[N-(2-pyridylmethylene)aniline]copper(II)
The Cu atom in the title compound, [Cu(NO(3))(2)(C(12)H(10)N(2))(CH(3)OH)], adopts a square-pyramidal geometry, being ligated by two N atoms of the bidentate N-(2-pyridylmethylene)aniline (ppma) ligand, two O atoms of NO(3) ligands and one O atom of a methanol molecule, which occupies the apical p...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971227/ https://www.ncbi.nlm.nih.gov/pubmed/21578116 http://dx.doi.org/10.1107/S1600536809041075 |
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author | Kim, Young-Inn Lee, Hong Woo Kim, Ji-Hoon Park, Sun Young Kang, Sung Kwon |
author_facet | Kim, Young-Inn Lee, Hong Woo Kim, Ji-Hoon Park, Sun Young Kang, Sung Kwon |
author_sort | Kim, Young-Inn |
collection | PubMed |
description | The Cu atom in the title compound, [Cu(NO(3))(2)(C(12)H(10)N(2))(CH(3)OH)], adopts a square-pyramidal geometry, being ligated by two N atoms of the bidentate N-(2-pyridylmethylene)aniline (ppma) ligand, two O atoms of NO(3) ligands and one O atom of a methanol molecule, which occupies the apical position. The phenyl ring on the ppma ligand is twisted out of the pyridine plane, forming a dihedral angle of 42.9 (1)°. In the crystal, intermolecular O—H⋯O hydrogen bonds between methanol and NO(3) ligands form an extensive one-dimensional network extending parallel to [100]. |
format | Text |
id | pubmed-2971227 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29712272010-12-30 Methanoldinitrato[N-(2-pyridylmethylene)aniline]copper(II) Kim, Young-Inn Lee, Hong Woo Kim, Ji-Hoon Park, Sun Young Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu atom in the title compound, [Cu(NO(3))(2)(C(12)H(10)N(2))(CH(3)OH)], adopts a square-pyramidal geometry, being ligated by two N atoms of the bidentate N-(2-pyridylmethylene)aniline (ppma) ligand, two O atoms of NO(3) ligands and one O atom of a methanol molecule, which occupies the apical position. The phenyl ring on the ppma ligand is twisted out of the pyridine plane, forming a dihedral angle of 42.9 (1)°. In the crystal, intermolecular O—H⋯O hydrogen bonds between methanol and NO(3) ligands form an extensive one-dimensional network extending parallel to [100]. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971227/ /pubmed/21578116 http://dx.doi.org/10.1107/S1600536809041075 Text en © Kim et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kim, Young-Inn Lee, Hong Woo Kim, Ji-Hoon Park, Sun Young Kang, Sung Kwon Methanoldinitrato[N-(2-pyridylmethylene)aniline]copper(II) |
title | Methanoldinitrato[N-(2-pyridylmethylene)aniline]copper(II) |
title_full | Methanoldinitrato[N-(2-pyridylmethylene)aniline]copper(II) |
title_fullStr | Methanoldinitrato[N-(2-pyridylmethylene)aniline]copper(II) |
title_full_unstemmed | Methanoldinitrato[N-(2-pyridylmethylene)aniline]copper(II) |
title_short | Methanoldinitrato[N-(2-pyridylmethylene)aniline]copper(II) |
title_sort | methanoldinitrato[n-(2-pyridylmethylene)aniline]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971227/ https://www.ncbi.nlm.nih.gov/pubmed/21578116 http://dx.doi.org/10.1107/S1600536809041075 |
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