N-(Fluoren-9-ylmethoxy­carbon­yl)-l-aspartic acid 4-tert-butyl ester

The bond distances and bond angles of the title compound, C(23)H(25)NO(6), are consistent with values typically found for fluoren-9-ylmethoxy­carbonyl-protected amino acids. The conformations of the backbone and the side chain are slightly different from those of l-aspartic acid. The crystal structu...

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Detalles Bibliográficos
Autores principales: Yamada, Kazuhiko, Hashizume, Daisuke, Shimizu, Tadashi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971228/
https://www.ncbi.nlm.nih.gov/pubmed/21578224
http://dx.doi.org/10.1107/S1600536809037611
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author Yamada, Kazuhiko
Hashizume, Daisuke
Shimizu, Tadashi
author_facet Yamada, Kazuhiko
Hashizume, Daisuke
Shimizu, Tadashi
author_sort Yamada, Kazuhiko
collection PubMed
description The bond distances and bond angles of the title compound, C(23)H(25)NO(6), are consistent with values typically found for fluoren-9-ylmethoxy­carbonyl-protected amino acids. The conformations of the backbone and the side chain are slightly different from those of l-aspartic acid. The crystal structure exhibits two inter­molecular hydrogen bonds, forming a two-dimensional sheet structure parallel to the ab plane.
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spelling pubmed-29712282010-12-30 N-(Fluoren-9-ylmethoxy­carbon­yl)-l-aspartic acid 4-tert-butyl ester Yamada, Kazuhiko Hashizume, Daisuke Shimizu, Tadashi Acta Crystallogr Sect E Struct Rep Online Organic Papers The bond distances and bond angles of the title compound, C(23)H(25)NO(6), are consistent with values typically found for fluoren-9-ylmethoxy­carbonyl-protected amino acids. The conformations of the backbone and the side chain are slightly different from those of l-aspartic acid. The crystal structure exhibits two inter­molecular hydrogen bonds, forming a two-dimensional sheet structure parallel to the ab plane. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971228/ /pubmed/21578224 http://dx.doi.org/10.1107/S1600536809037611 Text en © Yamada et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yamada, Kazuhiko
Hashizume, Daisuke
Shimizu, Tadashi
N-(Fluoren-9-ylmethoxy­carbon­yl)-l-aspartic acid 4-tert-butyl ester
title N-(Fluoren-9-ylmethoxy­carbon­yl)-l-aspartic acid 4-tert-butyl ester
title_full N-(Fluoren-9-ylmethoxy­carbon­yl)-l-aspartic acid 4-tert-butyl ester
title_fullStr N-(Fluoren-9-ylmethoxy­carbon­yl)-l-aspartic acid 4-tert-butyl ester
title_full_unstemmed N-(Fluoren-9-ylmethoxy­carbon­yl)-l-aspartic acid 4-tert-butyl ester
title_short N-(Fluoren-9-ylmethoxy­carbon­yl)-l-aspartic acid 4-tert-butyl ester
title_sort n-(fluoren-9-ylmethoxy­carbon­yl)-l-aspartic acid 4-tert-butyl ester
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971228/
https://www.ncbi.nlm.nih.gov/pubmed/21578224
http://dx.doi.org/10.1107/S1600536809037611
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AT hashizumedaisuke nfluoren9ylmethoxycarbonyllasparticacid4tertbutylester
AT shimizutadashi nfluoren9ylmethoxycarbonyllasparticacid4tertbutylester

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