Aqua[N-(2,5-dihydroxybenzyl)imino­diacetato]copper(II)

The title complex, [Cu(C(11)H(11)NO(6))(H(2)O)], contains a Cu(II) atom in a distorted square-pyramidal geometry. The metal centre is coordinated in the basal sites by one water mol­ecule and two carboxyl­ate O atoms and one N atom of the tetra­dentate ligand [Cu—O range, 1.9376 (11)–1.9541 (12), Cu...

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Detalles Bibliográficos
Autores principales: Zhang, Xiu-Qing, Huang, Fu-Ping, Bian, He-Dong, Yu, Qing, Liang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971235/
https://www.ncbi.nlm.nih.gov/pubmed/21578137
http://dx.doi.org/10.1107/S1600536809042238
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author Zhang, Xiu-Qing
Huang, Fu-Ping
Bian, He-Dong
Yu, Qing
Liang, Hong
author_facet Zhang, Xiu-Qing
Huang, Fu-Ping
Bian, He-Dong
Yu, Qing
Liang, Hong
author_sort Zhang, Xiu-Qing
collection PubMed
description The title complex, [Cu(C(11)H(11)NO(6))(H(2)O)], contains a Cu(II) atom in a distorted square-pyramidal geometry. The metal centre is coordinated in the basal sites by one water mol­ecule and two carboxyl­ate O atoms and one N atom of the tetra­dentate ligand [Cu—O range, 1.9376 (11)–1.9541 (12), Cu—N, 1.9929 (12) Å] while the apical site is occupied by a hydro­quinone O donor atom [Cu—O, 2.3746 (12) Å]. Inter­molecular hydrogen bonding inter­actions involving both hydro­quinone hydr­oxy groups and the coordinated water as donors give a three-dimensional framework structure.
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spelling pubmed-29712352010-12-30 Aqua[N-(2,5-dihydroxybenzyl)imino­diacetato]copper(II) Zhang, Xiu-Qing Huang, Fu-Ping Bian, He-Dong Yu, Qing Liang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(11)H(11)NO(6))(H(2)O)], contains a Cu(II) atom in a distorted square-pyramidal geometry. The metal centre is coordinated in the basal sites by one water mol­ecule and two carboxyl­ate O atoms and one N atom of the tetra­dentate ligand [Cu—O range, 1.9376 (11)–1.9541 (12), Cu—N, 1.9929 (12) Å] while the apical site is occupied by a hydro­quinone O donor atom [Cu—O, 2.3746 (12) Å]. Inter­molecular hydrogen bonding inter­actions involving both hydro­quinone hydr­oxy groups and the coordinated water as donors give a three-dimensional framework structure. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971235/ /pubmed/21578137 http://dx.doi.org/10.1107/S1600536809042238 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiu-Qing
Huang, Fu-Ping
Bian, He-Dong
Yu, Qing
Liang, Hong
Aqua[N-(2,5-dihydroxybenzyl)imino­diacetato]copper(II)
title Aqua[N-(2,5-dihydroxybenzyl)imino­diacetato]copper(II)
title_full Aqua[N-(2,5-dihydroxybenzyl)imino­diacetato]copper(II)
title_fullStr Aqua[N-(2,5-dihydroxybenzyl)imino­diacetato]copper(II)
title_full_unstemmed Aqua[N-(2,5-dihydroxybenzyl)imino­diacetato]copper(II)
title_short Aqua[N-(2,5-dihydroxybenzyl)imino­diacetato]copper(II)
title_sort aqua[n-(2,5-dihydroxybenzyl)imino­diacetato]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971235/
https://www.ncbi.nlm.nih.gov/pubmed/21578137
http://dx.doi.org/10.1107/S1600536809042238
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